Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one

In the racemic title compound, C(20)H(16)N(2)O(5), the pyran ring adopts a shallow envelope conformation, with the stereogenic C atom displaced from the other atoms by 0.273 (2) Å. The dihedral angle between the fused-ring system and the pendant p-tolyl group is 87.62 (7)°. The mol­ecular conformati...

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Autores principales: Govindaraj, J., AaminaNaaz, Y., Kamalraja, Jayabal, Perumal, Paramasivam T., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350753/
https://www.ncbi.nlm.nih.gov/pubmed/25844225
http://dx.doi.org/10.1107/S205698901500225X
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author Govindaraj, J.
AaminaNaaz, Y.
Kamalraja, Jayabal
Perumal, Paramasivam T.
SubbiahPandi, A.
author_facet Govindaraj, J.
AaminaNaaz, Y.
Kamalraja, Jayabal
Perumal, Paramasivam T.
SubbiahPandi, A.
author_sort Govindaraj, J.
collection PubMed
description In the racemic title compound, C(20)H(16)N(2)O(5), the pyran ring adopts a shallow envelope conformation, with the stereogenic C atom displaced from the other atoms by 0.273 (2) Å. The dihedral angle between the fused-ring system and the pendant p-tolyl group is 87.62 (7)°. The mol­ecular conformation is consolidated by an intra­molecular N—H⋯O hydrogen bond, which generates an S(6) ring. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, resulting in [010] chains.
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spelling pubmed-43507532015-04-03 Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one Govindaraj, J. AaminaNaaz, Y. Kamalraja, Jayabal Perumal, Paramasivam T. SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports In the racemic title compound, C(20)H(16)N(2)O(5), the pyran ring adopts a shallow envelope conformation, with the stereogenic C atom displaced from the other atoms by 0.273 (2) Å. The dihedral angle between the fused-ring system and the pendant p-tolyl group is 87.62 (7)°. The mol­ecular conformation is consolidated by an intra­molecular N—H⋯O hydrogen bond, which generates an S(6) ring. In the crystal, mol­ecules are linked by C—H⋯O inter­actions, resulting in [010] chains. International Union of Crystallography 2015-02-07 /pmc/articles/PMC4350753/ /pubmed/25844225 http://dx.doi.org/10.1107/S205698901500225X Text en © Govindaraj et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Govindaraj, J.
AaminaNaaz, Y.
Kamalraja, Jayabal
Perumal, Paramasivam T.
SubbiahPandi, A.
Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one
title Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one
title_full Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one
title_fullStr Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one
title_full_unstemmed Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one
title_short Crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4H)-one
title_sort crystal structure of 2-methyl­amino-3-nitro-4-p-tolyl­pyrano[3,2-c]chromen-5(4h)-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350753/
https://www.ncbi.nlm.nih.gov/pubmed/25844225
http://dx.doi.org/10.1107/S205698901500225X
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