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Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2) N (3),S]palladium(II)
The whole molecule of the title complex, [Pd(C(15)H(21)N(2)S(2))(2)], is generated by twofold rotational symmetry. The palladium(II) atom exhibits a square-planar coordination geometry, and is located on the crystallographic twofold axis that induces a cis configuration of the N,S chelating ligands...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350759/ https://www.ncbi.nlm.nih.gov/pubmed/25844210 http://dx.doi.org/10.1107/S2056989015002236 |
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| author | Begum, M. Sabina Howlader, M. Belayet Hossain Sheikh, M. Chanmiya Miyatake, Ryuta Zangrando, Ennio |
| author_facet | Begum, M. Sabina Howlader, M. Belayet Hossain Sheikh, M. Chanmiya Miyatake, Ryuta Zangrando, Ennio |
| author_sort | Begum, M. Sabina |
| collection | PubMed |
| description | The whole molecule of the title complex, [Pd(C(15)H(21)N(2)S(2))(2)], is generated by twofold rotational symmetry. The palladium(II) atom exhibits a square-planar coordination geometry, and is located on the crystallographic twofold axis that induces a cis configuration of the N,S chelating ligands. In the crystal, molecules stack along the c-axis direction and there are no significant intermolecular interactions present. The structure was refined as an inversion twin with a final BASF parameter of 0.34 (2). |
| format | Online Article Text |
| id | pubmed-4350759 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-43507592015-04-03 Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2) N (3),S]palladium(II) Begum, M. Sabina Howlader, M. Belayet Hossain Sheikh, M. Chanmiya Miyatake, Ryuta Zangrando, Ennio Acta Crystallogr E Crystallogr Commun Data Reports The whole molecule of the title complex, [Pd(C(15)H(21)N(2)S(2))(2)], is generated by twofold rotational symmetry. The palladium(II) atom exhibits a square-planar coordination geometry, and is located on the crystallographic twofold axis that induces a cis configuration of the N,S chelating ligands. In the crystal, molecules stack along the c-axis direction and there are no significant intermolecular interactions present. The structure was refined as an inversion twin with a final BASF parameter of 0.34 (2). International Union of Crystallography 2015-02-11 /pmc/articles/PMC4350759/ /pubmed/25844210 http://dx.doi.org/10.1107/S2056989015002236 Text en © Begum et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Begum, M. Sabina Howlader, M. Belayet Hossain Sheikh, M. Chanmiya Miyatake, Ryuta Zangrando, Ennio Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2) N (3),S]palladium(II) |
| title | Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2)
N
(3),S]palladium(II) |
| title_full | Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2)
N
(3),S]palladium(II) |
| title_fullStr | Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2)
N
(3),S]palladium(II) |
| title_full_unstemmed | Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2)
N
(3),S]palladium(II) |
| title_short | Crystal structure of bis[S-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2)
N
(3),S]palladium(II) |
| title_sort | crystal structure of bis[s-hexyl 3-(4-methylbenzylidene)dithiocarbazato-κ(2)
n
(3),s]palladium(ii) |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350759/ https://www.ncbi.nlm.nih.gov/pubmed/25844210 http://dx.doi.org/10.1107/S2056989015002236 |
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