Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate

In the crystal structure of the title salt, (C(10)H(10)N(2))[ZnCl(4)], the bi­pyridine­diium dication is not planar, with a dihedral angle of 37.21 (9)° between the planes of the two pyridine rings. In the crystal, the slightly distorted [ZnCl(4)](2−) anions are packed into rods parallel to [001], w...

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Autores principales: Govindaraj, Jeyaraman, Thirumurugan, Subramani, Clara, Antoni Samy, Anbalagan, Krishnamoorthy, SubbiahPandi, Arunachalathevar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350760/
https://www.ncbi.nlm.nih.gov/pubmed/25844212
http://dx.doi.org/10.1107/S2056989015003175
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author Govindaraj, Jeyaraman
Thirumurugan, Subramani
Clara, Antoni Samy
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalathevar
author_facet Govindaraj, Jeyaraman
Thirumurugan, Subramani
Clara, Antoni Samy
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalathevar
author_sort Govindaraj, Jeyaraman
collection PubMed
description In the crystal structure of the title salt, (C(10)H(10)N(2))[ZnCl(4)], the bi­pyridine­diium dication is not planar, with a dihedral angle of 37.21 (9)° between the planes of the two pyridine rings. In the crystal, the slightly distorted [ZnCl(4)](2−) anions are packed into rods parallel to [001], with the organic cations arranged in corrugated layers parallel to (100). Cations and anions are linked through N—H⋯Cl hydrogen bonds, forming chains parallel to [20-1]. Additional C—H⋯Cl inter­actions consolidate the crystal packing.
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spelling pubmed-43507602015-04-03 Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate Govindaraj, Jeyaraman Thirumurugan, Subramani Clara, Antoni Samy Anbalagan, Krishnamoorthy SubbiahPandi, Arunachalathevar Acta Crystallogr E Crystallogr Commun Data Reports In the crystal structure of the title salt, (C(10)H(10)N(2))[ZnCl(4)], the bi­pyridine­diium dication is not planar, with a dihedral angle of 37.21 (9)° between the planes of the two pyridine rings. In the crystal, the slightly distorted [ZnCl(4)](2−) anions are packed into rods parallel to [001], with the organic cations arranged in corrugated layers parallel to (100). Cations and anions are linked through N—H⋯Cl hydrogen bonds, forming chains parallel to [20-1]. Additional C—H⋯Cl inter­actions consolidate the crystal packing. International Union of Crystallography 2015-02-21 /pmc/articles/PMC4350760/ /pubmed/25844212 http://dx.doi.org/10.1107/S2056989015003175 Text en © Govindaraj et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Govindaraj, Jeyaraman
Thirumurugan, Subramani
Clara, Antoni Samy
Anbalagan, Krishnamoorthy
SubbiahPandi, Arunachalathevar
Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate
title Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate
title_full Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate
title_fullStr Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate
title_full_unstemmed Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate
title_short Crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate
title_sort crystal structure of 2,2′-bi­pyridine-1,1′-diium tetra­chlorido­zincate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4350760/
https://www.ncbi.nlm.nih.gov/pubmed/25844212
http://dx.doi.org/10.1107/S2056989015003175
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