Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs

Two tetrakis(phthalocyaninato) dysprosium(III)-cadmium(II) single-molecule magnets (SMMs) with different extent of phthalocyanine peripheral substitution and therefore different coordination geometry for the Dy ions were revealed to exhibit different SMM behavior, providing an easy way to tuning and...

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Detalles Bibliográficos
Autores principales: Shang, Hong, Zeng, Suyuan, Wang, Hailong, Dou, Jianmin, Jiang, Jianzhuang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4351535/
https://www.ncbi.nlm.nih.gov/pubmed/25744587
http://dx.doi.org/10.1038/srep08838
Descripción
Sumario:Two tetrakis(phthalocyaninato) dysprosium(III)-cadmium(II) single-molecule magnets (SMMs) with different extent of phthalocyanine peripheral substitution and therefore different coordination geometry for the Dy ions were revealed to exhibit different SMM behavior, providing an easy way to tuning and controlling the molecular structure and in turn the magnetic properties of tetrakis(tetrapyrrole) lanthanide SMMs through simple tetrapyrrole peripheral substitution.

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