Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs

Two tetrakis(phthalocyaninato) dysprosium(III)-cadmium(II) single-molecule magnets (SMMs) with different extent of phthalocyanine peripheral substitution and therefore different coordination geometry for the Dy ions were revealed to exhibit different SMM behavior, providing an easy way to tuning and...

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Detalles Bibliográficos
Autores principales: Shang, Hong, Zeng, Suyuan, Wang, Hailong, Dou, Jianmin, Jiang, Jianzhuang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4351535/
https://www.ncbi.nlm.nih.gov/pubmed/25744587
http://dx.doi.org/10.1038/srep08838
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author Shang, Hong
Zeng, Suyuan
Wang, Hailong
Dou, Jianmin
Jiang, Jianzhuang
author_facet Shang, Hong
Zeng, Suyuan
Wang, Hailong
Dou, Jianmin
Jiang, Jianzhuang
author_sort Shang, Hong
collection PubMed
description Two tetrakis(phthalocyaninato) dysprosium(III)-cadmium(II) single-molecule magnets (SMMs) with different extent of phthalocyanine peripheral substitution and therefore different coordination geometry for the Dy ions were revealed to exhibit different SMM behavior, providing an easy way to tuning and controlling the molecular structure and in turn the magnetic properties of tetrakis(tetrapyrrole) lanthanide SMMs through simple tetrapyrrole peripheral substitution.
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spelling pubmed-43515352015-03-10 Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs Shang, Hong Zeng, Suyuan Wang, Hailong Dou, Jianmin Jiang, Jianzhuang Sci Rep Article Two tetrakis(phthalocyaninato) dysprosium(III)-cadmium(II) single-molecule magnets (SMMs) with different extent of phthalocyanine peripheral substitution and therefore different coordination geometry for the Dy ions were revealed to exhibit different SMM behavior, providing an easy way to tuning and controlling the molecular structure and in turn the magnetic properties of tetrakis(tetrapyrrole) lanthanide SMMs through simple tetrapyrrole peripheral substitution. Nature Publishing Group 2015-03-06 /pmc/articles/PMC4351535/ /pubmed/25744587 http://dx.doi.org/10.1038/srep08838 Text en Copyright © 2015, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder in order to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Shang, Hong
Zeng, Suyuan
Wang, Hailong
Dou, Jianmin
Jiang, Jianzhuang
Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs
title Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs
title_full Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs
title_fullStr Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs
title_full_unstemmed Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs
title_short Peripheral Substitution: An Easy Way to Tuning the Magnetic Behavior of Tetrakis(phthalocyaninato) Dysprosium(III) SMMs
title_sort peripheral substitution: an easy way to tuning the magnetic behavior of tetrakis(phthalocyaninato) dysprosium(iii) smms
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4351535/
https://www.ncbi.nlm.nih.gov/pubmed/25744587
http://dx.doi.org/10.1038/srep08838
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