Cargando…

Enhanced Photoluminescence and Raman Properties of Al-Doped ZnO Nanostructures Prepared Using Thermal Chemical Vapor Deposition of Methanol Assisted with Heated Brass

Vapor phase transport (VPT) assisted by mixture of methanol and acetone via thermal evaporation of brass (CuZn) was used to prepare un-doped and Al-doped zinc oxide (ZnO) nanostructures (NSs). The structure and morphology were characterized by field emission scanning electron microscopy (FESEM) and...

Descripción completa

Detalles Bibliográficos
Autores principales: Thandavan, Tamil Many K., Gani, Siti Meriam Abdul, San Wong, Chiow, Md. Nor, Roslan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4355069/
https://www.ncbi.nlm.nih.gov/pubmed/25756598
http://dx.doi.org/10.1371/journal.pone.0121756
Descripción
Sumario:Vapor phase transport (VPT) assisted by mixture of methanol and acetone via thermal evaporation of brass (CuZn) was used to prepare un-doped and Al-doped zinc oxide (ZnO) nanostructures (NSs). The structure and morphology were characterized by field emission scanning electron microscopy (FESEM) and x-ray diffraction (XRD). Photoluminescence (PL) properties of un-doped and Al-doped ZnO showed significant changes in the optical properties providing evidence for several types of defects such as zinc interstitials (Zn(i)), oxygen interstitials (O(i)), zinc vacancy (V(zn)), singly charged zinc vacancy (V(Zn) (-)), oxygen vacancy (V(o)), singly charged oxygen vacancy (V(o) (+)) and oxygen anti-site defects (O(Zn)) in the grown NSs. The Al-doped ZnO NSs have exhibited shifted PL peaks at near band edge (NBE) and red luminescence compared to the un-doped ZnO. The Raman scattering results provided evidence of Al doping into the ZnO NSs due to peak shift from 145 cm(-1) to an anomalous peak at 138 cm(-1). Presence of enhanced Raman signal at around 274 and 743 cm(-1) further confirmed Al in ZnO NSs. The enhanced D and G band in all Al-doped ZnO NSs shows possible functionalization and doping process in ZnO NSs.