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Regiocontrol in Catalytic Reductive Couplings through Alterations of Silane Rate Dependence
[Image: see text] Combinations of ligand, reducing agent, and reaction conditions have been identified that allow alteration in the rate- and regioselectivity-determining step of nickel-catalyzed aldehyde–alkyne reductive couplings. Whereas previously developed protocols involve metallacycle-forming...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4356119/ https://www.ncbi.nlm.nih.gov/pubmed/25531576 http://dx.doi.org/10.1021/ja511778a |