A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability

We prepared new and scalable, hybrid inorganic–organic step-growth hydrogels with polyhedral oligomeric silsesquioxane (POSS) network knot construction elements and hydrolytically degradable poly(ethylene glycol) (PEG) di-ester macromonomers by in situ radical-mediated thiol–ene photopolymerization....

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Detalles Bibliográficos
Autores principales: Alves, F., Nischang, I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4360384/
https://www.ncbi.nlm.nih.gov/pubmed/25821524
http://dx.doi.org/10.1039/c4py01789g
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author Alves, F.
Nischang, I.
author_facet Alves, F.
Nischang, I.
author_sort Alves, F.
collection PubMed
description We prepared new and scalable, hybrid inorganic–organic step-growth hydrogels with polyhedral oligomeric silsesquioxane (POSS) network knot construction elements and hydrolytically degradable poly(ethylene glycol) (PEG) di-ester macromonomers by in situ radical-mediated thiol–ene photopolymerization. The physicochemical properties of the gels are fine-tailored over orders of magnitude including functionalization of their interior, a hierarchical gel structure, and biodegradability.
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spelling pubmed-43603842015-03-26 A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability Alves, F. Nischang, I. Polym Chem Chemistry We prepared new and scalable, hybrid inorganic–organic step-growth hydrogels with polyhedral oligomeric silsesquioxane (POSS) network knot construction elements and hydrolytically degradable poly(ethylene glycol) (PEG) di-ester macromonomers by in situ radical-mediated thiol–ene photopolymerization. The physicochemical properties of the gels are fine-tailored over orders of magnitude including functionalization of their interior, a hierarchical gel structure, and biodegradability. Royal Society of Chemistry 2015-03-28 2015-02-11 /pmc/articles/PMC4360384/ /pubmed/25821524 http://dx.doi.org/10.1039/c4py01789g Text en This journal is © The Royal Society of Chemistry 2015 https://creativecommons.org/licenses/by/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/ (https://creativecommons.org/licenses/by/3.0/) ) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Alves, F.
Nischang, I.
A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability
title A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability
title_full A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability
title_fullStr A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability
title_full_unstemmed A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability
title_short A simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability
title_sort simple approach to hybrid inorganic–organic step-growth hydrogels with scalable control of physicochemical properties and biodegradability
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4360384/
https://www.ncbi.nlm.nih.gov/pubmed/25821524
http://dx.doi.org/10.1039/c4py01789g
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AT alvesf simpleapproachtohybridinorganicorganicstepgrowthhydrogelswithscalablecontrolofphysicochemicalpropertiesandbiodegradability
AT nischangi simpleapproachtohybridinorganicorganicstepgrowthhydrogelswithscalablecontrolofphysicochemicalpropertiesandbiodegradability

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