3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates

3α,5α-Cyclocholestan-6β-yl alkyl and aryl ethers were proved to be efficient cholesteryl donors in the electrochemical synthesis of glycoconjugates. 3α,5α-Cyclocholestan-6β-ol (i-cholesterol) and its tert-butyldimethylsilyl ether can also be used for this purpose. The i-cholesterol derivatives show...

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Autores principales: Tomkiel, Aneta M, Biedrzycki, Adam, Płoszyńska, Jolanta, Naróg, Dorota, Sobkowiak, Andrzej, Morzycki, Jacek W
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4362039/
https://www.ncbi.nlm.nih.gov/pubmed/25815065
http://dx.doi.org/10.3762/bjoc.11.16
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author Tomkiel, Aneta M
Biedrzycki, Adam
Płoszyńska, Jolanta
Naróg, Dorota
Sobkowiak, Andrzej
Morzycki, Jacek W
author_facet Tomkiel, Aneta M
Biedrzycki, Adam
Płoszyńska, Jolanta
Naróg, Dorota
Sobkowiak, Andrzej
Morzycki, Jacek W
author_sort Tomkiel, Aneta M
collection PubMed
description 3α,5α-Cyclocholestan-6β-yl alkyl and aryl ethers were proved to be efficient cholesteryl donors in the electrochemical synthesis of glycoconjugates. 3α,5α-Cyclocholestan-6β-ol (i-cholesterol) and its tert-butyldimethylsilyl ether can also be used for this purpose. The i-cholesterol derivatives show similar reactivities to those of previously studied 3α,5α-cyclocholestan-6β-thioethers.
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spelling pubmed-43620392015-03-26 3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates Tomkiel, Aneta M Biedrzycki, Adam Płoszyńska, Jolanta Naróg, Dorota Sobkowiak, Andrzej Morzycki, Jacek W Beilstein J Org Chem Full Research Paper 3α,5α-Cyclocholestan-6β-yl alkyl and aryl ethers were proved to be efficient cholesteryl donors in the electrochemical synthesis of glycoconjugates. 3α,5α-Cyclocholestan-6β-ol (i-cholesterol) and its tert-butyldimethylsilyl ether can also be used for this purpose. The i-cholesterol derivatives show similar reactivities to those of previously studied 3α,5α-cyclocholestan-6β-thioethers. Beilstein-Institut 2015-01-26 /pmc/articles/PMC4362039/ /pubmed/25815065 http://dx.doi.org/10.3762/bjoc.11.16 Text en Copyright © 2015, Tomkiel et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Tomkiel, Aneta M
Biedrzycki, Adam
Płoszyńska, Jolanta
Naróg, Dorota
Sobkowiak, Andrzej
Morzycki, Jacek W
3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
title 3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
title_full 3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
title_fullStr 3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
title_full_unstemmed 3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
title_short 3α,5α-Cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
title_sort 3α,5α-cyclocholestan-6β-yl ethers as donors of the cholesterol moiety for the electrochemical synthesis of cholesterol glycoconjugates
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4362039/
https://www.ncbi.nlm.nih.gov/pubmed/25815065
http://dx.doi.org/10.3762/bjoc.11.16
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