Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8)

The mixed-metal oxo clusters FeTi(5)O(4)(OiPr)(4)(OMc)(10) (OMc = methacrylate), Zn(2)Ti(4)O(4)(OiPr)(2)(OMc)(10), Cd(4)Ti(2)O(2)(OAc)(2)(OMc)(10)(HOiPr)(2), [Ca(2)Ti(4)O(4)(OAc)(2)(OMc)(10)](n), and [Sr(2)Ti(4)O(4)(OMc)(12)(HOMc)(2)](n) were obtained from the reaction of titanium alkoxides with the...

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Detalles Bibliográficos
Autores principales: Artner, Christine, Koyun, Ayse, Czakler, Matthias, Schubert, Ulrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4362470/
https://www.ncbi.nlm.nih.gov/pubmed/25814833
http://dx.doi.org/10.1002/ejic.201402499
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author Artner, Christine
Koyun, Ayse
Czakler, Matthias
Schubert, Ulrich
author_facet Artner, Christine
Koyun, Ayse
Czakler, Matthias
Schubert, Ulrich
author_sort Artner, Christine
collection PubMed
description The mixed-metal oxo clusters FeTi(5)O(4)(OiPr)(4)(OMc)(10) (OMc = methacrylate), Zn(2)Ti(4)O(4)(OiPr)(2)(OMc)(10), Cd(4)Ti(2)O(2)(OAc)(2)(OMc)(10)(HOiPr)(2), [Ca(2)Ti(4)O(4)(OAc)(2)(OMc)(10)](n), and [Sr(2)Ti(4)O(4)(OMc)(12)(HOMc)(2)](n) were obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition Ti(6)O(4)(OR)(8)(OOCR′)(8). The Ca and Sr derivatives consist of chains of condensed clusters.
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spelling pubmed-43624702015-03-24 Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8) Artner, Christine Koyun, Ayse Czakler, Matthias Schubert, Ulrich Eur J Inorg Chem Full Papers The mixed-metal oxo clusters FeTi(5)O(4)(OiPr)(4)(OMc)(10) (OMc = methacrylate), Zn(2)Ti(4)O(4)(OiPr)(2)(OMc)(10), Cd(4)Ti(2)O(2)(OAc)(2)(OMc)(10)(HOiPr)(2), [Ca(2)Ti(4)O(4)(OAc)(2)(OMc)(10)](n), and [Sr(2)Ti(4)O(4)(OMc)(12)(HOMc)(2)](n) were obtained from the reaction of titanium alkoxides with the corresponding metal acetates and methacrylic acid. Their structures are derived from Ti clusters with the composition Ti(6)O(4)(OR)(8)(OOCR′)(8). The Ca and Sr derivatives consist of chains of condensed clusters. WILEY-VCH Verlag 2014-10 2014-08-15 /pmc/articles/PMC4362470/ /pubmed/25814833 http://dx.doi.org/10.1002/ejic.201402499 Text en © 2014 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/ © 2014 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Full Papers
Artner, Christine
Koyun, Ayse
Czakler, Matthias
Schubert, Ulrich
Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8)
title Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8)
title_full Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8)
title_fullStr Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8)
title_full_unstemmed Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8)
title_short Mixed-Metal Oxo Clusters Structurally Derived from Ti(6)O(4)(OR)(8)(OOCR′)(8)
title_sort mixed-metal oxo clusters structurally derived from ti(6)o(4)(or)(8)(oocr′)(8)
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4362470/
https://www.ncbi.nlm.nih.gov/pubmed/25814833
http://dx.doi.org/10.1002/ejic.201402499
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AT czaklermatthias mixedmetaloxoclustersstructurallyderivedfromti6o4or8oocr8
AT schubertulrich mixedmetaloxoclustersstructurallyderivedfromti6o4or8oocr8

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