Detailed Characterization of a Nanosecond-Lived Excited State: X-ray and Theoretical Investigation of the Quintet State in Photoexcited [Fe(terpy)(2)](2+)

[Image: see text] Theoretical predictions show that depending on the populations of the Fe 3d(xy), 3d(xz), and 3d(yz) orbitals two possible quintet states can exist for the high-spin state of the photoswitchable model system [Fe(terpy)(2)](2+). The differences in the structure and molecular properti...

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Detalles Bibliográficos
Autores principales: Vankó, György, Bordage, Amélie, Pápai, Mátyás, Haldrup, Kristoffer, Glatzel, Pieter, March, Anne Marie, Doumy, Gilles, Britz, Alexander, Galler, Andreas, Assefa, Tadesse, Cabaret, Delphine, Juhin, Amélie, van Driel, Tim B., Kjær, Kasper S., Dohn, Asmus, Møller, Klaus B., Lemke, Henrik T., Gallo, Erik, Rovezzi, Mauro, Németh, Zoltán, Rozsályi, Emese, Rozgonyi, Tamás, Uhlig, Jens, Sundström, Villy, Nielsen, Martin M., Young, Linda, Southworth, Stephen H., Bressler, Christian, Gawelda, Wojciech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4368081/
https://www.ncbi.nlm.nih.gov/pubmed/25838847
http://dx.doi.org/10.1021/acs.jpcc.5b00557

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