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Identification of Ice Nucleation Active Sites on Feldspar Dust Particles

[Image: see text] Mineral dusts originating from Earth’s crust are known to be important atmospheric ice nuclei. In agreement with earlier studies, feldspar was found as the most active of the tested natural mineral dusts. Here we investigated in closer detail the reasons for its activity and the di...

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Detalles Bibliográficos
Autores principales: Zolles, Tobias, Burkart, Julia, Häusler, Thomas, Pummer, Bernhard, Hitzenberger, Regina, Grothe, Hinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4368087/
https://www.ncbi.nlm.nih.gov/pubmed/25584435
http://dx.doi.org/10.1021/jp509839x
Descripción
Sumario:[Image: see text] Mineral dusts originating from Earth’s crust are known to be important atmospheric ice nuclei. In agreement with earlier studies, feldspar was found as the most active of the tested natural mineral dusts. Here we investigated in closer detail the reasons for its activity and the difference in the activity of the different feldspars. Conclusions are drawn from scanning electron microscopy, X-ray powder diffraction, infrared spectroscopy, and oil-immersion freezing experiments. K-feldspar showed by far the highest ice nucleation activity. Finally, we give a potential explanation of this effect, finding alkali-metal ions having different hydration shells and thus an influence on the ice nucleation activity of feldspar surfaces.