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Identification of Ice Nucleation Active Sites on Feldspar Dust Particles

[Image: see text] Mineral dusts originating from Earth’s crust are known to be important atmospheric ice nuclei. In agreement with earlier studies, feldspar was found as the most active of the tested natural mineral dusts. Here we investigated in closer detail the reasons for its activity and the di...

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Autores principales: Zolles, Tobias, Burkart, Julia, Häusler, Thomas, Pummer, Bernhard, Hitzenberger, Regina, Grothe, Hinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4368087/
https://www.ncbi.nlm.nih.gov/pubmed/25584435
http://dx.doi.org/10.1021/jp509839x
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author Zolles, Tobias
Burkart, Julia
Häusler, Thomas
Pummer, Bernhard
Hitzenberger, Regina
Grothe, Hinrich
author_facet Zolles, Tobias
Burkart, Julia
Häusler, Thomas
Pummer, Bernhard
Hitzenberger, Regina
Grothe, Hinrich
author_sort Zolles, Tobias
collection PubMed
description [Image: see text] Mineral dusts originating from Earth’s crust are known to be important atmospheric ice nuclei. In agreement with earlier studies, feldspar was found as the most active of the tested natural mineral dusts. Here we investigated in closer detail the reasons for its activity and the difference in the activity of the different feldspars. Conclusions are drawn from scanning electron microscopy, X-ray powder diffraction, infrared spectroscopy, and oil-immersion freezing experiments. K-feldspar showed by far the highest ice nucleation activity. Finally, we give a potential explanation of this effect, finding alkali-metal ions having different hydration shells and thus an influence on the ice nucleation activity of feldspar surfaces.
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spelling pubmed-43680872015-03-31 Identification of Ice Nucleation Active Sites on Feldspar Dust Particles Zolles, Tobias Burkart, Julia Häusler, Thomas Pummer, Bernhard Hitzenberger, Regina Grothe, Hinrich J Phys Chem A [Image: see text] Mineral dusts originating from Earth’s crust are known to be important atmospheric ice nuclei. In agreement with earlier studies, feldspar was found as the most active of the tested natural mineral dusts. Here we investigated in closer detail the reasons for its activity and the difference in the activity of the different feldspars. Conclusions are drawn from scanning electron microscopy, X-ray powder diffraction, infrared spectroscopy, and oil-immersion freezing experiments. K-feldspar showed by far the highest ice nucleation activity. Finally, we give a potential explanation of this effect, finding alkali-metal ions having different hydration shells and thus an influence on the ice nucleation activity of feldspar surfaces. American Chemical Society 2015-01-13 2015-03-19 /pmc/articles/PMC4368087/ /pubmed/25584435 http://dx.doi.org/10.1021/jp509839x Text en Copyright © 2015 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Zolles, Tobias
Burkart, Julia
Häusler, Thomas
Pummer, Bernhard
Hitzenberger, Regina
Grothe, Hinrich
Identification of Ice Nucleation Active Sites on Feldspar Dust Particles
title Identification of Ice Nucleation Active Sites on Feldspar Dust Particles
title_full Identification of Ice Nucleation Active Sites on Feldspar Dust Particles
title_fullStr Identification of Ice Nucleation Active Sites on Feldspar Dust Particles
title_full_unstemmed Identification of Ice Nucleation Active Sites on Feldspar Dust Particles
title_short Identification of Ice Nucleation Active Sites on Feldspar Dust Particles
title_sort identification of ice nucleation active sites on feldspar dust particles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4368087/
https://www.ncbi.nlm.nih.gov/pubmed/25584435
http://dx.doi.org/10.1021/jp509839x
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