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Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N(3)Pt(2+) Catalysts
[Image: see text] The combination of the N-based pincer ligand PyBOX with Pt(2+) leads to new catalysts for the enantioselective cycloisomerization of dienyl- and trienyl-ols. The mechanistic combination of electrophilic cyclization followed by rapid protodemetalation is surprising and leads to a po...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4372115/ https://www.ncbi.nlm.nih.gov/pubmed/25838970 http://dx.doi.org/10.1021/cs401190c |