Reversible Mechanical Switching of Magnetic Interactions in a Molecular Shuttle

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An acid–base switchable molecular shuttle based on a [2]rotaxane, incorporating stable radical units in both the ring and dumbbell components, is reported. The [2]rotaxane comprises a dibenzo[24]crown-8 ring (DB24C8) interlocked with a dumbbell component that possesses a dialkylammonium (NH(2)(+)) a...

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Detalles Bibliográficos
Autores principales: Bleve, Valentina, Schäfer, Christian, Franchi, Paola, Silvi, Serena, Mezzina, Elisabetta, Credi, Alberto, Lucarini, Marco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: BlackWell Publishing Ltd 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4380948/
https://www.ncbi.nlm.nih.gov/pubmed/25861565
http://dx.doi.org/10.1002/open.201402073
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