BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids

A symmetrical BODIPY–BODIPY dyad with a diyne linker was prepared in two steps; the lifetime decay of this rotor appeared to correlate with the viscosity of the media, thus making this dyad a suitable small molecule viscometer for molecular solvents. The potential of using the rotor to probe the vis...

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Detalles Bibliográficos
Autores principales: Kimball, Joseph D., Raut, Sangram, Jameson, Laramie P., Smith, Nicholas W., Gryczynski, Zygmunt, Dzyuba, Sergei V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4381807/
https://www.ncbi.nlm.nih.gov/pubmed/25844163
http://dx.doi.org/10.1039/c4ra09757b
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author Kimball, Joseph D.
Raut, Sangram
Jameson, Laramie P.
Smith, Nicholas W.
Gryczynski, Zygmunt
Dzyuba, Sergei V.
author_facet Kimball, Joseph D.
Raut, Sangram
Jameson, Laramie P.
Smith, Nicholas W.
Gryczynski, Zygmunt
Dzyuba, Sergei V.
author_sort Kimball, Joseph D.
collection PubMed
description A symmetrical BODIPY–BODIPY dyad with a diyne linker was prepared in two steps; the lifetime decay of this rotor appeared to correlate with the viscosity of the media, thus making this dyad a suitable small molecule viscometer for molecular solvents. The potential of using the rotor to probe the viscosity of ionic liquids was also investigated.
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spelling pubmed-43818072015-04-15 BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids Kimball, Joseph D. Raut, Sangram Jameson, Laramie P. Smith, Nicholas W. Gryczynski, Zygmunt Dzyuba, Sergei V. RSC Adv Chemistry A symmetrical BODIPY–BODIPY dyad with a diyne linker was prepared in two steps; the lifetime decay of this rotor appeared to correlate with the viscosity of the media, thus making this dyad a suitable small molecule viscometer for molecular solvents. The potential of using the rotor to probe the viscosity of ionic liquids was also investigated. Royal Society of Chemistry 2015-03-21 2015-02-17 /pmc/articles/PMC4381807/ /pubmed/25844163 http://dx.doi.org/10.1039/c4ra09757b Text en This journal is © The Royal Society of Chemistry 2015 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Kimball, Joseph D.
Raut, Sangram
Jameson, Laramie P.
Smith, Nicholas W.
Gryczynski, Zygmunt
Dzyuba, Sergei V.
BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids
title BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids
title_full BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids
title_fullStr BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids
title_full_unstemmed BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids
title_short BODIPY–BODIPY dyad: assessing the potential as a viscometer for molecular and ionic liquids
title_sort bodipy–bodipy dyad: assessing the potential as a viscometer for molecular and ionic liquids
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4381807/
https://www.ncbi.nlm.nih.gov/pubmed/25844163
http://dx.doi.org/10.1039/c4ra09757b
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