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Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea

In the title compound, C(13)H(13)N(3)O, the phenyl ring makes a dihedral angle of 47.0 (1)° with the mean plane of the –NC(=O)N– unit, while the dihedral angle between the latter mean plane and the amino­phenyl ring is 84.43 (7)°. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds involv...

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Autores principales: Mague, Joel T., Mohamed, Shaaban K., Akkurt, Mehmet, Omran, Omran A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384537/
https://www.ncbi.nlm.nih.gov/pubmed/25878886
http://dx.doi.org/10.1107/S2056989014028175
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author Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Omran, Omran A.
Albayati, Mustafa R.
author_facet Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Omran, Omran A.
Albayati, Mustafa R.
author_sort Mague, Joel T.
collection PubMed
description In the title compound, C(13)H(13)N(3)O, the phenyl ring makes a dihedral angle of 47.0 (1)° with the mean plane of the –NC(=O)N– unit, while the dihedral angle between the latter mean plane and the amino­phenyl ring is 84.43 (7)°. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds involving the central –NHC(=O)NH– units, forming chains running parallel to the b axis. These chains associate with one another via N—H⋯O and N—H⋯N hydrogen bonds, from the pendant amino groups to the –NHC(=O)NH– units of adjacent mol­ecules, forming columns propagating along [010]. The structure was refined as a two-component twin with a 0.933 (3):0.067 (3) domain ratio.
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spelling pubmed-43845372015-04-15 Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea Mague, Joel T. Mohamed, Shaaban K. Akkurt, Mehmet Omran, Omran A. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(13)H(13)N(3)O, the phenyl ring makes a dihedral angle of 47.0 (1)° with the mean plane of the –NC(=O)N– unit, while the dihedral angle between the latter mean plane and the amino­phenyl ring is 84.43 (7)°. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds involving the central –NHC(=O)NH– units, forming chains running parallel to the b axis. These chains associate with one another via N—H⋯O and N—H⋯N hydrogen bonds, from the pendant amino groups to the –NHC(=O)NH– units of adjacent mol­ecules, forming columns propagating along [010]. The structure was refined as a two-component twin with a 0.933 (3):0.067 (3) domain ratio. International Union of Crystallography 2015-01-10 /pmc/articles/PMC4384537/ /pubmed/25878886 http://dx.doi.org/10.1107/S2056989014028175 Text en © Mague et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mague, Joel T.
Mohamed, Shaaban K.
Akkurt, Mehmet
Omran, Omran A.
Albayati, Mustafa R.
Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea
title Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea
title_full Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea
title_fullStr Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea
title_full_unstemmed Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea
title_short Crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea
title_sort crystal structure of 1-(2-amino­phen­yl)-3-phenyl­urea
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384537/
https://www.ncbi.nlm.nih.gov/pubmed/25878886
http://dx.doi.org/10.1107/S2056989014028175
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