Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)

In the title compound, C(10)H(10)Cl(2)N(2)O(2), the secondary amide groups are differently twisted relative to the benzene ring, with dihedral angles between the respective planes of 21.03 (2) and 81.22 (2)°. In the crystal, the mol­ecules are connected by N—H⋯O and C—H⋯O hydrogen bonds, forming a t...

Descripción completa

Detalles Bibliográficos
Autores principales: Tariq, Javaria, Murtaza, Shahzad, Tahir, Muhammad Nawaz, Zaheer, Muhammad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384540/
https://www.ncbi.nlm.nih.gov/pubmed/25878855
http://dx.doi.org/10.1107/S2056989015000304
_version_ 1782364915147735040
author Tariq, Javaria
Murtaza, Shahzad
Tahir, Muhammad Nawaz
Zaheer, Muhammad
author_facet Tariq, Javaria
Murtaza, Shahzad
Tahir, Muhammad Nawaz
Zaheer, Muhammad
author_sort Tariq, Javaria
collection PubMed
description In the title compound, C(10)H(10)Cl(2)N(2)O(2), the secondary amide groups are differently twisted relative to the benzene ring, with dihedral angles between the respective planes of 21.03 (2) and 81.22 (2)°. In the crystal, the mol­ecules are connected by N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional polymeric network parallel to (001). One of the amide carbonyl O atoms accepts two H atoms in N—H⋯O and C—H⋯O inter­actions, forming an R (2) (2)(6) ring motif.
format Online
Article
Text
id pubmed-4384540
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-43845402015-04-15 Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide) Tariq, Javaria Murtaza, Shahzad Tahir, Muhammad Nawaz Zaheer, Muhammad Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(10)H(10)Cl(2)N(2)O(2), the secondary amide groups are differently twisted relative to the benzene ring, with dihedral angles between the respective planes of 21.03 (2) and 81.22 (2)°. In the crystal, the mol­ecules are connected by N—H⋯O and C—H⋯O hydrogen bonds, forming a two-dimensional polymeric network parallel to (001). One of the amide carbonyl O atoms accepts two H atoms in N—H⋯O and C—H⋯O inter­actions, forming an R (2) (2)(6) ring motif. International Union of Crystallography 2015-01-14 /pmc/articles/PMC4384540/ /pubmed/25878855 http://dx.doi.org/10.1107/S2056989015000304 Text en © Tariq et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Tariq, Javaria
Murtaza, Shahzad
Tahir, Muhammad Nawaz
Zaheer, Muhammad
Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)
title Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)
title_full Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)
title_fullStr Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)
title_full_unstemmed Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)
title_short Crystal structure of N,N′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)
title_sort crystal structure of n,n′-(1,2-phenyl­ene)bis­(2-chloro­acetamide)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384540/
https://www.ncbi.nlm.nih.gov/pubmed/25878855
http://dx.doi.org/10.1107/S2056989015000304
work_keys_str_mv AT tariqjavaria crystalstructureofnn12phenylenebis2chloroacetamide
AT murtazashahzad crystalstructureofnn12phenylenebis2chloroacetamide
AT tahirmuhammadnawaz crystalstructureofnn12phenylenebis2chloroacetamide
AT zaheermuhammad crystalstructureofnn12phenylenebis2chloroacetamide

Ejemplares similares