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Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4)
In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thiocyanate anions in a slightly distorted octahedral geometry. The asymmetric unit consists of a Ni(2+) cati...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384548/ https://www.ncbi.nlm.nih.gov/pubmed/25878833 http://dx.doi.org/10.1107/S2056989014026991 |
Sumario: | In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thiocyanate anions in a slightly distorted octahedral geometry. The asymmetric unit consists of a Ni(2+) cation located on a centre of inversion, two water molecules and one thiocyanate ligand, as well as two uncoordinated 2,5-dimethylpyrazine ligands in general positions. In the crystal, discrete complex molecules are linked into a three-dimensional network by O—H⋯N hydrogen bonding between the water H atoms and the 2,5-dimethylpyrazine N atoms. |
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