Cargando…
Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4)
In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thiocyanate anions in a slightly distorted octahedral geometry. The asymmetric unit consists of a Ni(2+) cati...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384548/ https://www.ncbi.nlm.nih.gov/pubmed/25878833 http://dx.doi.org/10.1107/S2056989014026991 |
_version_ | 1782364916935557120 |
---|---|
author | Suckert, Stefan Wriedt, Mario Jess, Inke Näther, Christian |
author_facet | Suckert, Stefan Wriedt, Mario Jess, Inke Näther, Christian |
author_sort | Suckert, Stefan |
collection | PubMed |
description | In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thiocyanate anions in a slightly distorted octahedral geometry. The asymmetric unit consists of a Ni(2+) cation located on a centre of inversion, two water molecules and one thiocyanate ligand, as well as two uncoordinated 2,5-dimethylpyrazine ligands in general positions. In the crystal, discrete complex molecules are linked into a three-dimensional network by O—H⋯N hydrogen bonding between the water H atoms and the 2,5-dimethylpyrazine N atoms. |
format | Online Article Text |
id | pubmed-4384548 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43845482015-04-15 Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4) Suckert, Stefan Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Data Reports In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thiocyanate anions in a slightly distorted octahedral geometry. The asymmetric unit consists of a Ni(2+) cation located on a centre of inversion, two water molecules and one thiocyanate ligand, as well as two uncoordinated 2,5-dimethylpyrazine ligands in general positions. In the crystal, discrete complex molecules are linked into a three-dimensional network by O—H⋯N hydrogen bonding between the water H atoms and the 2,5-dimethylpyrazine N atoms. International Union of Crystallography 2015-01-03 /pmc/articles/PMC4384548/ /pubmed/25878833 http://dx.doi.org/10.1107/S2056989014026991 Text en © Suckert et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Suckert, Stefan Wriedt, Mario Jess, Inke Näther, Christian Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4) |
title | Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4) |
title_full | Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4) |
title_fullStr | Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4) |
title_full_unstemmed | Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4) |
title_short | Crystal structure of tetraaquabis(thiocyanato-κN)nickel(II)–2,5-dimethylpyrazine (1/4) |
title_sort | crystal structure of tetraaquabis(thiocyanato-κn)nickel(ii)–2,5-dimethylpyrazine (1/4) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384548/ https://www.ncbi.nlm.nih.gov/pubmed/25878833 http://dx.doi.org/10.1107/S2056989014026991 |
work_keys_str_mv | AT suckertstefan crystalstructureoftetraaquabisthiocyanatoknnickelii25dimethylpyrazine14 AT wriedtmario crystalstructureoftetraaquabisthiocyanatoknnickelii25dimethylpyrazine14 AT jessinke crystalstructureoftetraaquabisthiocyanatoknnickelii25dimethylpyrazine14 AT natherchristian crystalstructureoftetraaquabisthiocyanatoknnickelii25dimethylpyrazine14 |