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Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4)

In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thio­cyanate anions in a slightly distorted octa­hedral geometry. The asymmetric unit consists of a Ni(2+) cati...

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Detalles Bibliográficos
Autores principales: Suckert, Stefan, Wriedt, Mario, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384548/
https://www.ncbi.nlm.nih.gov/pubmed/25878833
http://dx.doi.org/10.1107/S2056989014026991
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author Suckert, Stefan
Wriedt, Mario
Jess, Inke
Näther, Christian
author_facet Suckert, Stefan
Wriedt, Mario
Jess, Inke
Näther, Christian
author_sort Suckert, Stefan
collection PubMed
description In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thio­cyanate anions in a slightly distorted octa­hedral geometry. The asymmetric unit consists of a Ni(2+) cation located on a centre of inversion, two water mol­ecules and one thio­cyanate ligand, as well as two uncoordinated 2,5-di­methyl­pyrazine ligands in general positions. In the crystal, discrete complex mol­ecules are linked into a three-dimensional network by O—H⋯N hydrogen bonding between the water H atoms and the 2,5-di­methyl­pyrazine N atoms.
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spelling pubmed-43845482015-04-15 Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4) Suckert, Stefan Wriedt, Mario Jess, Inke Näther, Christian Acta Crystallogr E Crystallogr Commun Data Reports In the crystal structure of the title compound, [Ni(NCS)(2)(H(2)O)(4)]·4C(6)H(8)N(2), the Ni(II) cations are coordinated by four water ligands and two trans-coordinated terminally N-bonded thio­cyanate anions in a slightly distorted octa­hedral geometry. The asymmetric unit consists of a Ni(2+) cation located on a centre of inversion, two water mol­ecules and one thio­cyanate ligand, as well as two uncoordinated 2,5-di­methyl­pyrazine ligands in general positions. In the crystal, discrete complex mol­ecules are linked into a three-dimensional network by O—H⋯N hydrogen bonding between the water H atoms and the 2,5-di­methyl­pyrazine N atoms. International Union of Crystallography 2015-01-03 /pmc/articles/PMC4384548/ /pubmed/25878833 http://dx.doi.org/10.1107/S2056989014026991 Text en © Suckert et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Suckert, Stefan
Wriedt, Mario
Jess, Inke
Näther, Christian
Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4)
title Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4)
title_full Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4)
title_fullStr Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4)
title_full_unstemmed Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4)
title_short Crystal structure of tetra­aqua­bis­(thio­cyanato-κN)nickel(II)–2,5-di­methyl­pyrazine (1/4)
title_sort crystal structure of tetra­aqua­bis­(thio­cyanato-κn)nickel(ii)–2,5-di­methyl­pyrazine (1/4)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384548/
https://www.ncbi.nlm.nih.gov/pubmed/25878833
http://dx.doi.org/10.1107/S2056989014026991
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