Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs

The crystal structures of two solvates of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl(3)(Me(3)P)(3)]·H(2)O, and one with methanol in the crystal lattice, fac-[RhCl(3)(Me(3)P)(3)]·0.5CH(3)OH. These rhodium compounds e...

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Detalles Bibliográficos
Autores principales: Merola, Joseph S., Franks, Marion A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384550/
https://www.ncbi.nlm.nih.gov/pubmed/25878826
http://dx.doi.org/10.1107/S2056989015001516
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author Merola, Joseph S.
Franks, Marion A.
author_facet Merola, Joseph S.
Franks, Marion A.
author_sort Merola, Joseph S.
collection PubMed
description The crystal structures of two solvates of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl(3)(Me(3)P)(3)]·H(2)O, and one with methanol in the crystal lattice, fac-[RhCl(3)(Me(3)P)(3)]·0.5CH(3)OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013 ▸). Polyhedron, 54, 67–73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.
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spelling pubmed-43845502015-04-15 Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs Merola, Joseph S. Franks, Marion A. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structures of two solvates of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl(3)(Me(3)P)(3)]·H(2)O, and one with methanol in the crystal lattice, fac-[RhCl(3)(Me(3)P)(3)]·0.5CH(3)OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merola et al. (2013 ▸). Polyhedron, 54, 67–73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships. International Union of Crystallography 2015-01-31 /pmc/articles/PMC4384550/ /pubmed/25878826 http://dx.doi.org/10.1107/S2056989015001516 Text en © Merola and Franks 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Merola, Joseph S.
Franks, Marion A.
Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
title Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
title_full Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
title_fullStr Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
title_full_unstemmed Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
title_short Crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
title_sort crystal structures of fac-tri­chlorido­tris­(tri­methyl­phosphane-κp)rhodium(iii) monohydrate and fac-tri­chlorido­tris­(tri­methyl­phosphane-κp)rhodium(iii) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384550/
https://www.ncbi.nlm.nih.gov/pubmed/25878826
http://dx.doi.org/10.1107/S2056989015001516
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AT franksmariona crystalstructuresoffactrichloridotristrimethylphosphanekprhodiumiiimonohydrateandfactrichloridotristrimethylphosphanekprhodiumiiimethanolhemisolvaterhodiumstructuresthatareisotypicwiththeiriridiumanalogs

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