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Crystal structure of aqua[N-(2-oxidobenzyl-κO)-l-leucinato-κ(2) N,O](1,10-phenanthroline-κ(2) N,N′)nickel(II) pentahydrate
In the title compound, [Ni(C(13)H(17)NO(3))(C(12)H(8)N(2))(H(2)O)]·5H(2)O, the Ni(II) atom is in a distorted octahedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hydroxybenzyl)amino]-4-methyl...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384555/ https://www.ncbi.nlm.nih.gov/pubmed/25878817 http://dx.doi.org/10.1107/S2056989015001085 |
Sumario: | In the title compound, [Ni(C(13)H(17)NO(3))(C(12)H(8)N(2))(H(2)O)]·5H(2)O, the Ni(II) atom is in a distorted octahedral coordination environment provided by the two N atoms of one bidentate phenanthroline ligand and two O atoms and one N atom from a tridentate 2-[(2-hydroxybenzyl)amino]-4-methylpentanoic acid (HAMA) ligand and one water molecule. The complex was prepared by the reaction of nickel(II) nitrate with HAMA in the presence of 1,10-phenanthroline in a 1:1:1 ratio. In the crystal, the complex molecules and solvate water molecules are associated via O—H⋯O hydrogen bonds into a three-dimensional network. |
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