The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione

In the title compound, C(19)H(16)N(4)S, the pyrazolo­[3,4-d]pyrimidine ring is close to being planar, with the greatest deviation from the mean plane being 0.023 (2) Å for the C atom bearing the thione S atom. The two phenyl rings are nearly perpendicular to the fused ring system [dihedral angles =...

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Autores principales: El Fal, Mohammed, Ramli, Youssef, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384557/
https://www.ncbi.nlm.nih.gov/pubmed/25878890
http://dx.doi.org/10.1107/S205698901402828X
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author El Fal, Mohammed
Ramli, Youssef
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_facet El Fal, Mohammed
Ramli, Youssef
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_sort El Fal, Mohammed
collection PubMed
description In the title compound, C(19)H(16)N(4)S, the pyrazolo­[3,4-d]pyrimidine ring is close to being planar, with the greatest deviation from the mean plane being 0.023 (2) Å for the C atom bearing the thione S atom. The two phenyl rings are nearly perpendicular to the fused ring system [dihedral angles = 71.4 (2) and 78.1 (2)°], but are oriented in opposite directions; the dihedral angle between the phenyl rings is 32.22 (16)°. In the crystal, linear supra­molecular chains along [101] are sustained by C—H⋯S inter­actions.
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spelling pubmed-43845572015-04-15 The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione El Fal, Mohammed Ramli, Youssef Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(19)H(16)N(4)S, the pyrazolo­[3,4-d]pyrimidine ring is close to being planar, with the greatest deviation from the mean plane being 0.023 (2) Å for the C atom bearing the thione S atom. The two phenyl rings are nearly perpendicular to the fused ring system [dihedral angles = 71.4 (2) and 78.1 (2)°], but are oriented in opposite directions; the dihedral angle between the phenyl rings is 32.22 (16)°. In the crystal, linear supra­molecular chains along [101] are sustained by C—H⋯S inter­actions. International Union of Crystallography 2015-01-10 /pmc/articles/PMC4384557/ /pubmed/25878890 http://dx.doi.org/10.1107/S205698901402828X Text en © El Fal et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
El Fal, Mohammed
Ramli, Youssef
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione
title The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione
title_full The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione
title_fullStr The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione
title_full_unstemmed The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione
title_short The crystal structure of 1,5-dibenzyl-1H-pyrazolo­[3,4-d]pyrimidine-4(5H)-thione
title_sort crystal structure of 1,5-dibenzyl-1h-pyrazolo­[3,4-d]pyrimidine-4(5h)-thione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384557/
https://www.ncbi.nlm.nih.gov/pubmed/25878890
http://dx.doi.org/10.1107/S205698901402828X
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