Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol

In the title Schiff base, C(13)H(9)Cl(2)NO(2), which arose from the condensation of 3,4-di­chloro­aniline with 2,3-di­hydroxy­benzaldehyde, the dihedral angle between the aromatic rings is 44.74 (13)°. Intra­molecular O—H⋯O and O—H⋯N hydrogen bonds close S(5) and S(6) rings, respectively. In the cry...

Descripción completa

Detalles Bibliográficos
Autores principales: Tahir, Muhammad Nawaz, Shad, Hazoor Ahmad, Rauf, Abdul, Khan, Abdul Haleem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384559/
https://www.ncbi.nlm.nih.gov/pubmed/25878871
http://dx.doi.org/10.1107/S2056989015001401
_version_ 1782364919516102656
author Tahir, Muhammad Nawaz
Shad, Hazoor Ahmad
Rauf, Abdul
Khan, Abdul Haleem
author_facet Tahir, Muhammad Nawaz
Shad, Hazoor Ahmad
Rauf, Abdul
Khan, Abdul Haleem
author_sort Tahir, Muhammad Nawaz
collection PubMed
description In the title Schiff base, C(13)H(9)Cl(2)NO(2), which arose from the condensation of 3,4-di­chloro­aniline with 2,3-di­hydroxy­benzaldehyde, the dihedral angle between the aromatic rings is 44.74 (13)°. Intra­molecular O—H⋯O and O—H⋯N hydrogen bonds close S(5) and S(6) rings, respectively. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(10) loops. A weak C—H⋯π inter­action is also observed.
format Online
Article
Text
id pubmed-4384559
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-43845592015-04-15 Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol Tahir, Muhammad Nawaz Shad, Hazoor Ahmad Rauf, Abdul Khan, Abdul Haleem Acta Crystallogr E Crystallogr Commun Data Reports In the title Schiff base, C(13)H(9)Cl(2)NO(2), which arose from the condensation of 3,4-di­chloro­aniline with 2,3-di­hydroxy­benzaldehyde, the dihedral angle between the aromatic rings is 44.74 (13)°. Intra­molecular O—H⋯O and O—H⋯N hydrogen bonds close S(5) and S(6) rings, respectively. In the crystal, inversion dimers linked by pairs of O—H⋯O hydrogen bonds generate R (2) (2)(10) loops. A weak C—H⋯π inter­action is also observed. International Union of Crystallography 2015-01-28 /pmc/articles/PMC4384559/ /pubmed/25878871 http://dx.doi.org/10.1107/S2056989015001401 Text en © Tahir et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Tahir, Muhammad Nawaz
Shad, Hazoor Ahmad
Rauf, Abdul
Khan, Abdul Haleem
Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol
title Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol
title_full Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol
title_fullStr Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol
title_full_unstemmed Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol
title_short Crystal structure of 3-{(E)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol
title_sort crystal structure of 3-{(e)-[(3,4-di­chloro­phen­yl)imino]­meth­yl}benzene-1,2-diol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384559/
https://www.ncbi.nlm.nih.gov/pubmed/25878871
http://dx.doi.org/10.1107/S2056989015001401
work_keys_str_mv AT tahirmuhammadnawaz crystalstructureof3e34dichlorophenyliminomethylbenzene12diol
AT shadhazoorahmad crystalstructureof3e34dichlorophenyliminomethylbenzene12diol
AT raufabdul crystalstructureof3e34dichlorophenyliminomethylbenzene12diol
AT khanabdulhaleem crystalstructureof3e34dichlorophenyliminomethylbenzene12diol

Ejemplares similares