Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt)

The title compound, [FePt(C(12)H(10)P)(C(13)H(13)Si)(C(18)H(15)P)(2)(CO)(3)]·0.5CH(2)Cl(2), represents an example of a phosphido-bridged heterobimetallic silyl complex; these are inter­esting precursors for the coordination and activation of small unsaturated organic mol­ecules. The μ(2)-PPh(2) liga...

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Autores principales: Mohamed, Ahmed Said, Jourdain, Isabelle, Knorr, Michael, Rousselin, Yoann, Kubicki, Marek M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384561/
https://www.ncbi.nlm.nih.gov/pubmed/25878830
http://dx.doi.org/10.1107/S2056989015001565
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author Mohamed, Ahmed Said
Jourdain, Isabelle
Knorr, Michael
Rousselin, Yoann
Kubicki, Marek M.
author_facet Mohamed, Ahmed Said
Jourdain, Isabelle
Knorr, Michael
Rousselin, Yoann
Kubicki, Marek M.
author_sort Mohamed, Ahmed Said
collection PubMed
description The title compound, [FePt(C(12)H(10)P)(C(13)H(13)Si)(C(18)H(15)P)(2)(CO)(3)]·0.5CH(2)Cl(2), represents an example of a phosphido-bridged heterobimetallic silyl complex; these are inter­esting precursors for the coordination and activation of small unsaturated organic mol­ecules. The μ(2)-PPh(2) ligand spans the iron and platinum atoms, which are connected via a metal–metal bond of 2.7738 (4) Å. In contrast to most other complexes of the [(OC)(3)Fe(SiR (3))(μ-PR (2))PtL (2)] family, where the iron-bound SiR (3) group is trans-arranged with respect to the μ(2)-PPh(2) ligand, the SiPh(2)Me ligand is roughly collinear with the Fe–Pt vector [Si—Fe—Pt = 169.07 (3)°].
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spelling pubmed-43845612015-04-15 Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt) Mohamed, Ahmed Said Jourdain, Isabelle Knorr, Michael Rousselin, Yoann Kubicki, Marek M. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [FePt(C(12)H(10)P)(C(13)H(13)Si)(C(18)H(15)P)(2)(CO)(3)]·0.5CH(2)Cl(2), represents an example of a phosphido-bridged heterobimetallic silyl complex; these are inter­esting precursors for the coordination and activation of small unsaturated organic mol­ecules. The μ(2)-PPh(2) ligand spans the iron and platinum atoms, which are connected via a metal–metal bond of 2.7738 (4) Å. In contrast to most other complexes of the [(OC)(3)Fe(SiR (3))(μ-PR (2))PtL (2)] family, where the iron-bound SiR (3) group is trans-arranged with respect to the μ(2)-PPh(2) ligand, the SiPh(2)Me ligand is roughly collinear with the Fe–Pt vector [Si—Fe—Pt = 169.07 (3)°]. International Union of Crystallography 2015-01-31 /pmc/articles/PMC4384561/ /pubmed/25878830 http://dx.doi.org/10.1107/S2056989015001565 Text en © Mohamed et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Mohamed, Ahmed Said
Jourdain, Isabelle
Knorr, Michael
Rousselin, Yoann
Kubicki, Marek M.
Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt)
title Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt)
title_full Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt)
title_fullStr Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt)
title_full_unstemmed Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt)
title_short Crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) P:P)(methyl­diphenyl­silyl-κSi)bis(tri­phenyl­phosphane-κP)iron(II)platinum(0)(Fe—Pt)
title_sort crystal structure of tricarbon­yl(μ-di­phenyl­phosphido-κ(2) p:p)(methyl­diphenyl­silyl-κsi)bis(tri­phenyl­phosphane-κp)iron(ii)platinum(0)(fe—pt)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384561/
https://www.ncbi.nlm.nih.gov/pubmed/25878830
http://dx.doi.org/10.1107/S2056989015001565
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