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Crystal structure of 1′,1′′-dimethyl-4′-(4-cholorophen­yl)di­spiro­[11H-indeno[1,2-b]quinoxaline-11,2′-pyrrolidine-3′,3′′-piperidin]-4′′-one

In the title compound, C(30)H(27)ClN(4)O, the central pyrrolidine ring adopts an envelope conformation with the methyl­ene C atom being the flap. The quinoxaline and indane rings are each essentially planar, with r.m.s. deviations of 0.027 (1) and 0.0417 (1) Å, respectively. The pyrrolidine ring for...

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Detalles Bibliográficos
Autores principales: Nagalakshmi, R.A., Suresh, J., Malathi, K., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384562/
https://www.ncbi.nlm.nih.gov/pubmed/25878875
http://dx.doi.org/10.1107/S2056989014027698
Descripción
Sumario:In the title compound, C(30)H(27)ClN(4)O, the central pyrrolidine ring adopts an envelope conformation with the methyl­ene C atom being the flap. The quinoxaline and indane rings are each essentially planar, with r.m.s. deviations of 0.027 (1) and 0.0417 (1) Å, respectively. The pyrrolidine ring forms dihedral angles of 88.25 (1) and 83.76 (1)° with the quinoxaline and indane rings, respectively. A weak intra­molecular C—H⋯N inter­action is observed. In the crystal, C—H⋯π inter­actions lead to supra­molecular chains along [101] that assemble in the ac plane. Connections along the b axis are of the type Cl⋯Cl [3.6538 (16) Å].