Cargando…
Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2) P,P′]platinum(II) dichloride chloroform pentasolvate
In the title compound, [Pt{Ph(2)P(CH(2))(3)PPh(2)}(2)]Cl(2)·5CHCl(3), the Pt(II) cations, located on a centre of inversion, is coordinated by two chelating diphosphane ligands in a geometry which is close to square-planar. The chelate rings adopt a chair conformation. The Pt(II) cations are arranged...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384563/ https://www.ncbi.nlm.nih.gov/pubmed/25878844 http://dx.doi.org/10.1107/S205698901500136X |
| _version_ | 1782364920436752384 |
|---|---|
| author | Anderson, Bradley G. Hoyte, Sarah A. Spencer, John L. |
| author_facet | Anderson, Bradley G. Hoyte, Sarah A. Spencer, John L. |
| author_sort | Anderson, Bradley G. |
| collection | PubMed |
| description | In the title compound, [Pt{Ph(2)P(CH(2))(3)PPh(2)}(2)]Cl(2)·5CHCl(3), the Pt(II) cations, located on a centre of inversion, is coordinated by two chelating diphosphane ligands in a geometry which is close to square-planar. The chelate rings adopt a chair conformation. The Pt(II) cations are arranged in layers separated by Cl(−) anions as well as CHCl(3) solvent molecules. While this complex has been reported previously [Anderson et al. (1983 ▸). Inorg. Chim. Acta, 76, L251–L252], this is the first time a structure has been determined. |
| format | Online Article Text |
| id | pubmed-4384563 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-43845632015-04-15 Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2) P,P′]platinum(II) dichloride chloroform pentasolvate Anderson, Bradley G. Hoyte, Sarah A. Spencer, John L. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Pt{Ph(2)P(CH(2))(3)PPh(2)}(2)]Cl(2)·5CHCl(3), the Pt(II) cations, located on a centre of inversion, is coordinated by two chelating diphosphane ligands in a geometry which is close to square-planar. The chelate rings adopt a chair conformation. The Pt(II) cations are arranged in layers separated by Cl(−) anions as well as CHCl(3) solvent molecules. While this complex has been reported previously [Anderson et al. (1983 ▸). Inorg. Chim. Acta, 76, L251–L252], this is the first time a structure has been determined. International Union of Crystallography 2015-01-28 /pmc/articles/PMC4384563/ /pubmed/25878844 http://dx.doi.org/10.1107/S205698901500136X Text en © Anderson et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Anderson, Bradley G. Hoyte, Sarah A. Spencer, John L. Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2) P,P′]platinum(II) dichloride chloroform pentasolvate |
| title | Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2)
P,P′]platinum(II) dichloride chloroform pentasolvate |
| title_full | Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2)
P,P′]platinum(II) dichloride chloroform pentasolvate |
| title_fullStr | Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2)
P,P′]platinum(II) dichloride chloroform pentasolvate |
| title_full_unstemmed | Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2)
P,P′]platinum(II) dichloride chloroform pentasolvate |
| title_short | Crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2)
P,P′]platinum(II) dichloride chloroform pentasolvate |
| title_sort | crystal structure of bis[1,3-bis(diphenylphosphanyl)propane-κ(2)
p,p′]platinum(ii) dichloride chloroform pentasolvate |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384563/ https://www.ncbi.nlm.nih.gov/pubmed/25878844 http://dx.doi.org/10.1107/S205698901500136X |
| work_keys_str_mv | AT andersonbradleyg crystalstructureofbis13bisdiphenylphosphanylpropanek2ppplatinumiidichloridechloroformpentasolvate AT hoytesaraha crystalstructureofbis13bisdiphenylphosphanylpropanek2ppplatinumiidichloridechloroformpentasolvate AT spencerjohnl crystalstructureofbis13bisdiphenylphosphanylpropanek2ppplatinumiidichloridechloroformpentasolvate |