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Crystal structure of dichloridobis(4-ethylaniline-κN)zinc
The title compound, [ZnCl(2)(C(8)H(11)N)(2)], was synthesized by the reaction of zinc dichloride and 4-ethylaniline. The Zn(2+) cation is coordinated by two Cl(−) anions and the N atoms of two 4-ethylaniline ligands, forming a distorted Zn(N(2)Cl(2)) tetrahedron. The dihedral angle between the tw...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384566/ https://www.ncbi.nlm.nih.gov/pubmed/25878835 http://dx.doi.org/10.1107/S2056989014027832 |
Sumario: | The title compound, [ZnCl(2)(C(8)H(11)N)(2)], was synthesized by the reaction of zinc dichloride and 4-ethylaniline. The Zn(2+) cation is coordinated by two Cl(−) anions and the N atoms of two 4-ethylaniline ligands, forming a distorted Zn(N(2)Cl(2)) tetrahedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N—H⋯Cl hydrogen bonds link the molecules into sheets perpendicular to the a axis. C—H⋯Cl interactions also occur. |
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