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Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc

The title compound, [ZnCl(2)(C(8)H(11)N)(2)], was synthesized by the reaction of zinc dichloride and 4-ethyl­aniline. The Zn(2+) cation is coordinated by two Cl(−) anions and the N atoms of two 4-ethyl­aniline ligands, forming a distorted Zn(N(2)Cl(2)) tetra­hedron. The dihedral angle between the tw...

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Detalles Bibliográficos
Autores principales: Govindaraj, J., Thirumurugan, S., Reddy, D. Snehalatha, Anbalagan, K., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384566/
https://www.ncbi.nlm.nih.gov/pubmed/25878835
http://dx.doi.org/10.1107/S2056989014027832
Descripción
Sumario:The title compound, [ZnCl(2)(C(8)H(11)N)(2)], was synthesized by the reaction of zinc dichloride and 4-ethyl­aniline. The Zn(2+) cation is coordinated by two Cl(−) anions and the N atoms of two 4-ethyl­aniline ligands, forming a distorted Zn(N(2)Cl(2)) tetra­hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N—H⋯Cl hydrogen bonds link the mol­ecules into sheets perpendicular to the a axis. C—H⋯Cl inter­actions also occur.