Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc

The title compound, [ZnCl(2)(C(8)H(11)N)(2)], was synthesized by the reaction of zinc dichloride and 4-ethyl­aniline. The Zn(2+) cation is coordinated by two Cl(−) anions and the N atoms of two 4-ethyl­aniline ligands, forming a distorted Zn(N(2)Cl(2)) tetra­hedron. The dihedral angle between the tw...

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Autores principales: Govindaraj, J., Thirumurugan, S., Reddy, D. Snehalatha, Anbalagan, K., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384566/
https://www.ncbi.nlm.nih.gov/pubmed/25878835
http://dx.doi.org/10.1107/S2056989014027832
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author Govindaraj, J.
Thirumurugan, S.
Reddy, D. Snehalatha
Anbalagan, K.
SubbiahPandi, A.
author_facet Govindaraj, J.
Thirumurugan, S.
Reddy, D. Snehalatha
Anbalagan, K.
SubbiahPandi, A.
author_sort Govindaraj, J.
collection PubMed
description The title compound, [ZnCl(2)(C(8)H(11)N)(2)], was synthesized by the reaction of zinc dichloride and 4-ethyl­aniline. The Zn(2+) cation is coordinated by two Cl(−) anions and the N atoms of two 4-ethyl­aniline ligands, forming a distorted Zn(N(2)Cl(2)) tetra­hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N—H⋯Cl hydrogen bonds link the mol­ecules into sheets perpendicular to the a axis. C—H⋯Cl inter­actions also occur.
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spelling pubmed-43845662015-04-15 Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc Govindaraj, J. Thirumurugan, S. Reddy, D. Snehalatha Anbalagan, K. SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [ZnCl(2)(C(8)H(11)N)(2)], was synthesized by the reaction of zinc dichloride and 4-ethyl­aniline. The Zn(2+) cation is coordinated by two Cl(−) anions and the N atoms of two 4-ethyl­aniline ligands, forming a distorted Zn(N(2)Cl(2)) tetra­hedron. The dihedral angle between the two benzene rings is 85.3 (2)° The Zn atom lies on a twofold rotation axis. The ethyl substituents are disordered over two sets of sites in a 0.74 (2):0.26 (2) ratio. In the crystal, N—H⋯Cl hydrogen bonds link the mol­ecules into sheets perpendicular to the a axis. C—H⋯Cl inter­actions also occur. International Union of Crystallography 2015-01-14 /pmc/articles/PMC4384566/ /pubmed/25878835 http://dx.doi.org/10.1107/S2056989014027832 Text en © Govindaraj et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Govindaraj, J.
Thirumurugan, S.
Reddy, D. Snehalatha
Anbalagan, K.
SubbiahPandi, A.
Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc
title Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc
title_full Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc
title_fullStr Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc
title_full_unstemmed Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc
title_short Crystal structure of di­chlorido­bis­(4-ethyl­aniline-κN)zinc
title_sort crystal structure of di­chlorido­bis­(4-ethyl­aniline-κn)zinc
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384566/
https://www.ncbi.nlm.nih.gov/pubmed/25878835
http://dx.doi.org/10.1107/S2056989014027832
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