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Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide

In the title salt, C(10)H(11)N(4)O(2) (+)·I(−), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral an...

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Autores principales: Belguedj, Roumaissa, Bouraiou, Abdelmalek, Merazig, Hocine, Belfaitah, Ali, Bouacida, Sofiane
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384567/
https://www.ncbi.nlm.nih.gov/pubmed/25878869
http://dx.doi.org/10.1107/S2056989015001541
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author Belguedj, Roumaissa
Bouraiou, Abdelmalek
Merazig, Hocine
Belfaitah, Ali
Bouacida, Sofiane
author_facet Belguedj, Roumaissa
Bouraiou, Abdelmalek
Merazig, Hocine
Belfaitah, Ali
Bouacida, Sofiane
author_sort Belguedj, Roumaissa
collection PubMed
description In the title salt, C(10)H(11)N(4)O(2) (+)·I(−), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 (6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The structure features two types of hydrogen bonds (C—H⋯O and C—H⋯I), viz. cation–anion and cation–cation, which lead to the form ation of a three-dimensional network.
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spelling pubmed-43845672015-04-15 Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide Belguedj, Roumaissa Bouraiou, Abdelmalek Merazig, Hocine Belfaitah, Ali Bouacida, Sofiane Acta Crystallogr E Crystallogr Commun Data Reports In the title salt, C(10)H(11)N(4)O(2) (+)·I(−), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 (6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The structure features two types of hydrogen bonds (C—H⋯O and C—H⋯I), viz. cation–anion and cation–cation, which lead to the form ation of a three-dimensional network. International Union of Crystallography 2015-01-28 /pmc/articles/PMC4384567/ /pubmed/25878869 http://dx.doi.org/10.1107/S2056989015001541 Text en © Belguedj et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Belguedj, Roumaissa
Bouraiou, Abdelmalek
Merazig, Hocine
Belfaitah, Ali
Bouacida, Sofiane
Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide
title Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide
title_full Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide
title_fullStr Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide
title_full_unstemmed Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide
title_short Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)meth­yl]pyridinium iodide
title_sort crystal structure of 1-[(1-methyl-5-nitro-1h-imidazol-2-yl)meth­yl]pyridinium iodide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384567/
https://www.ncbi.nlm.nih.gov/pubmed/25878869
http://dx.doi.org/10.1107/S2056989015001541
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