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Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide
In the title salt, C(10)H(11)N(4)O(2) (+)·I(−), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral an...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384567/ https://www.ncbi.nlm.nih.gov/pubmed/25878869 http://dx.doi.org/10.1107/S2056989015001541 |
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author | Belguedj, Roumaissa Bouraiou, Abdelmalek Merazig, Hocine Belfaitah, Ali Bouacida, Sofiane |
author_facet | Belguedj, Roumaissa Bouraiou, Abdelmalek Merazig, Hocine Belfaitah, Ali Bouacida, Sofiane |
author_sort | Belguedj, Roumaissa |
collection | PubMed |
description | In the title salt, C(10)H(11)N(4)O(2) (+)·I(−), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 (6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The structure features two types of hydrogen bonds (C—H⋯O and C—H⋯I), viz. cation–anion and cation–cation, which lead to the form ation of a three-dimensional network. |
format | Online Article Text |
id | pubmed-4384567 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43845672015-04-15 Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide Belguedj, Roumaissa Bouraiou, Abdelmalek Merazig, Hocine Belfaitah, Ali Bouacida, Sofiane Acta Crystallogr E Crystallogr Commun Data Reports In the title salt, C(10)H(11)N(4)O(2) (+)·I(−), the asymmetric unit consists of a pyridinium cation bearning a (1-methyl-5-nitro-1H-imidazol-2-yl)methyl group at the N position and an iodide anion. The imidazole ring is quasiplanar, with a maxiumum deviation of 0.0032 (16) Å, and forms a dihedral angle of 67.39 (6)° with the plane of the pyridinium ring. The crystal packing can be described as alternating zigzag layers of cations parallel to the (001) plane, which are sandwiched by the iodide ions. The structure features two types of hydrogen bonds (C—H⋯O and C—H⋯I), viz. cation–anion and cation–cation, which lead to the form ation of a three-dimensional network. International Union of Crystallography 2015-01-28 /pmc/articles/PMC4384567/ /pubmed/25878869 http://dx.doi.org/10.1107/S2056989015001541 Text en © Belguedj et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Belguedj, Roumaissa Bouraiou, Abdelmalek Merazig, Hocine Belfaitah, Ali Bouacida, Sofiane Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
title | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
title_full | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
title_fullStr | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
title_full_unstemmed | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
title_short | Crystal structure of 1-[(1-methyl-5-nitro-1H-imidazol-2-yl)methyl]pyridinium iodide |
title_sort | crystal structure of 1-[(1-methyl-5-nitro-1h-imidazol-2-yl)methyl]pyridinium iodide |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384567/ https://www.ncbi.nlm.nih.gov/pubmed/25878869 http://dx.doi.org/10.1107/S2056989015001541 |
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