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Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate
The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate molecule and a solvent water molecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water molecule and a C—H⋯O contact from the organic mol...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384571/ https://www.ncbi.nlm.nih.gov/pubmed/25878881 http://dx.doi.org/10.1107/S2056989014027819 |
Sumario: | The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate molecule and a solvent water molecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water molecule and a C—H⋯O contact from the organic molecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90 (7)°. The azomethine bond [1.275 (2) Å] distance is very close to the formal C=N bond length, which confirms the azomethine bond formation. An extensive set of O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds builds a two-dimensional network progressing along the c axis. |
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