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Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate
The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate molecule and a solvent water molecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water molecule and a C—H⋯O contact from the organic mol...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384571/ https://www.ncbi.nlm.nih.gov/pubmed/25878881 http://dx.doi.org/10.1107/S2056989014027819 |
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author | Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Datta, Riya |
collection | PubMed |
description | The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate molecule and a solvent water molecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water molecule and a C—H⋯O contact from the organic molecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90 (7)°. The azomethine bond [1.275 (2) Å] distance is very close to the formal C=N bond length, which confirms the azomethine bond formation. An extensive set of O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds builds a two-dimensional network progressing along the c axis. |
format | Online Article Text |
id | pubmed-4384571 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43845712015-04-15 Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazinylidene]methyl}phenyl acetate molecule and a solvent water molecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water molecule and a C—H⋯O contact from the organic molecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90 (7)°. The azomethine bond [1.275 (2) Å] distance is very close to the formal C=N bond length, which confirms the azomethine bond formation. An extensive set of O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds builds a two-dimensional network progressing along the c axis. International Union of Crystallography 2015-01-03 /pmc/articles/PMC4384571/ /pubmed/25878881 http://dx.doi.org/10.1107/S2056989014027819 Text en © Datta et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate |
title | Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate |
title_full | Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate |
title_fullStr | Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate |
title_full_unstemmed | Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate |
title_short | Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate |
title_sort | crystal structure of 4-{(e)-[2-(pyridin-4-ylcarbonyl)hydrazin-1-ylidene]methyl}phenyl acetate monohydrate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384571/ https://www.ncbi.nlm.nih.gov/pubmed/25878881 http://dx.doi.org/10.1107/S2056989014027819 |
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