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Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate

The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazinyl­idene]meth­yl}phenyl acetate mol­ecule and a solvent water mol­ecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water mol­ecule and a C—H⋯O contact from the organic mol...

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Autores principales: Datta, Riya, Ramya, V., Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384571/
https://www.ncbi.nlm.nih.gov/pubmed/25878881
http://dx.doi.org/10.1107/S2056989014027819
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author Datta, Riya
Ramya, V.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Datta, Riya
Ramya, V.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Datta, Riya
collection PubMed
description The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazinyl­idene]meth­yl}phenyl acetate mol­ecule and a solvent water mol­ecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water mol­ecule and a C—H⋯O contact from the organic mol­ecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90 (7)°. The azomethine bond [1.275 (2) Å] distance is very close to the formal C=N bond length, which confirms the azomethine bond formation. An extensive set of O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds builds a two-dimensional network progressing along the c axis.
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spelling pubmed-43845712015-04-15 Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate Datta, Riya Ramya, V. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, C(15)H(13)N(3)O(3)·H(2)O, comprises a 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazinyl­idene]meth­yl}phenyl acetate mol­ecule and a solvent water mol­ecule linked by O—H⋯O and O—H⋯N hydrogen bonds from the water mol­ecule and a C—H⋯O contact from the organic mol­ecule. The compound adopts an E conformation with respect to the azomethine bond and the dihedral angle between the pyridine and benzene rings is 21.90 (7)°. The azomethine bond [1.275 (2) Å] distance is very close to the formal C=N bond length, which confirms the azomethine bond formation. An extensive set of O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds builds a two-dimensional network progressing along the c axis. International Union of Crystallography 2015-01-03 /pmc/articles/PMC4384571/ /pubmed/25878881 http://dx.doi.org/10.1107/S2056989014027819 Text en © Datta et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Datta, Riya
Ramya, V.
Sithambaresan, M.
Kurup, M. R. Prathapachandra
Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate
title Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate
title_full Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate
title_fullStr Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate
title_full_unstemmed Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate
title_short Crystal structure of 4-{(E)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate
title_sort crystal structure of 4-{(e)-[2-(pyridin-4-ylcarbon­yl)hydrazin-1-yl­idene]meth­yl}phenyl acetate monohydrate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384571/
https://www.ncbi.nlm.nih.gov/pubmed/25878881
http://dx.doi.org/10.1107/S2056989014027819
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