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Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene

In the cyclo­hexene ring of the title compound, C(23)H(20)BrNO(3)S, the –(CH(2))(4)– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thio­phene...

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Detalles Bibliográficos
Autores principales: Kaur, Manpreet, Jasinski, Jerry P., Yathirajan, H. S., Glidewell, Christopher, Byrappa, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384575/
https://www.ncbi.nlm.nih.gov/pubmed/25878812
http://dx.doi.org/10.1107/S2056989015000195
Descripción
Sumario:In the cyclo­hexene ring of the title compound, C(23)H(20)BrNO(3)S, the –(CH(2))(4)– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thio­phene ring and those of the benzene and phenyl rings are 35.2 (4) and 57.7 (3)°, respectively. The planes of the two aryl rings are twisted with respect to each other by 86.4 (6)°. In the mol­ecule, there is an O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains parallel to [100].