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Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene

In the cyclo­hexene ring of the title compound, C(23)H(20)BrNO(3)S, the –(CH(2))(4)– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thio­phene...

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Autores principales: Kaur, Manpreet, Jasinski, Jerry P., Yathirajan, H. S., Glidewell, Christopher, Byrappa, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384575/
https://www.ncbi.nlm.nih.gov/pubmed/25878812
http://dx.doi.org/10.1107/S2056989015000195
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author Kaur, Manpreet
Jasinski, Jerry P.
Yathirajan, H. S.
Glidewell, Christopher
Byrappa, K.
author_facet Kaur, Manpreet
Jasinski, Jerry P.
Yathirajan, H. S.
Glidewell, Christopher
Byrappa, K.
author_sort Kaur, Manpreet
collection PubMed
description In the cyclo­hexene ring of the title compound, C(23)H(20)BrNO(3)S, the –(CH(2))(4)– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thio­phene ring and those of the benzene and phenyl rings are 35.2 (4) and 57.7 (3)°, respectively. The planes of the two aryl rings are twisted with respect to each other by 86.4 (6)°. In the mol­ecule, there is an O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains parallel to [100].
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spelling pubmed-43845752015-04-15 Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene Kaur, Manpreet Jasinski, Jerry P. Yathirajan, H. S. Glidewell, Christopher Byrappa, K. Acta Crystallogr E Crystallogr Commun Research Communications In the cyclo­hexene ring of the title compound, C(23)H(20)BrNO(3)S, the –(CH(2))(4)– atoms are positionally disordered [occupancy ratio = 0.753 (6):0.247 (6)]. The ring has a half-chair conformation for both the major and minor components. The dihedral angles between the mean plane of the thio­phene ring and those of the benzene and phenyl rings are 35.2 (4) and 57.7 (3)°, respectively. The planes of the two aryl rings are twisted with respect to each other by 86.4 (6)°. In the mol­ecule, there is an O—H⋯N hydrogen bond forming an S(6) ring motif. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming chains parallel to [100]. International Union of Crystallography 2015-01-17 /pmc/articles/PMC4384575/ /pubmed/25878812 http://dx.doi.org/10.1107/S2056989015000195 Text en © Kaur et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kaur, Manpreet
Jasinski, Jerry P.
Yathirajan, H. S.
Glidewell, Christopher
Byrappa, K.
Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene
title Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene
title_full Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene
title_fullStr Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene
title_full_unstemmed Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene
title_short Crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene
title_sort crystal structure of 3-benzoyl-2-[(5-bromo-2-hydroxy-3-meth­oxy­benzyl­idene)amino]-4,5,6,7-tetra­hydro­benzo[b]thio­phene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384575/
https://www.ncbi.nlm.nih.gov/pubmed/25878812
http://dx.doi.org/10.1107/S2056989015000195
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