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Crystal structure of dibromido(N,N-dimethylformamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methylidene]ethanamine-κN}cadmium
In the mononuclear title complex, [CdBr(2)(C(20)H(17)N(3))(C(3)H(7)NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd(2+) atom is distorted trigonal bipyramidal, the axial positions being...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384581/ https://www.ncbi.nlm.nih.gov/pubmed/25878841 http://dx.doi.org/10.1107/S2056989015000778 |
Sumario: | In the mononuclear title complex, [CdBr(2)(C(20)H(17)N(3))(C(3)H(7)NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-ylmethylene)ethanamine (IQME), the coordination geometry around the Cd(2+) atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one dimethylformamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the Cd(II) atom from the equatorial plane being 0.046 (1) Å. An intramolecular C—H⋯Br interaction occurs. In the crystal, N—H⋯Br interactions generate [101] chains. |
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