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Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium

In the mononuclear title complex, [CdBr(2)(C(20)H(17)N(3))(C(3)H(7)NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-yl­methyl­ene)ethan­amine (IQME), the coordination geometry around the Cd(2+) atom is distorted trigonal bipyramidal, the axial positions being...

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Autores principales: Faizi, Md. Serajul Haque, Sharkina, Natalia O., Davydenko, Yuliya M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384581/
https://www.ncbi.nlm.nih.gov/pubmed/25878841
http://dx.doi.org/10.1107/S2056989015000778
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author Faizi, Md. Serajul Haque
Sharkina, Natalia O.
Davydenko, Yuliya M.
author_facet Faizi, Md. Serajul Haque
Sharkina, Natalia O.
Davydenko, Yuliya M.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description In the mononuclear title complex, [CdBr(2)(C(20)H(17)N(3))(C(3)H(7)NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-yl­methyl­ene)ethan­amine (IQME), the coordination geometry around the Cd(2+) atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one di­methyl­formamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the Cd(II) atom from the equatorial plane being 0.046 (1) Å. An intra­molecular C—H⋯Br inter­action occurs. In the crystal, N—H⋯Br inter­actions generate [101] chains.
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spelling pubmed-43845812015-04-15 Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium Faizi, Md. Serajul Haque Sharkina, Natalia O. Davydenko, Yuliya M. Acta Crystallogr E Crystallogr Commun Data Reports In the mononuclear title complex, [CdBr(2)(C(20)H(17)N(3))(C(3)H(7)NO)], synthesized from the quinoline-derived Schiff base 2-(1H-indol-3-yl)-N-(quinolin-2-yl­methyl­ene)ethan­amine (IQME), the coordination geometry around the Cd(2+) atom is distorted trigonal bipyramidal, the axial positions being occupied by the quinoline N atom [Cd—N = 2.401 (3) Å] and one di­methyl­formamide O-atom donor [Cd—O = 2.399 (2) Å]. The equatorial plane is formed by the imine N atom [Cd—N = 2.293 (3) Å] and two bromides [Cd—Br = 2.5621 (8) and 2.5676 (8) Å], with the deviation of the Cd(II) atom from the equatorial plane being 0.046 (1) Å. An intra­molecular C—H⋯Br inter­action occurs. In the crystal, N—H⋯Br inter­actions generate [101] chains. International Union of Crystallography 2015-01-21 /pmc/articles/PMC4384581/ /pubmed/25878841 http://dx.doi.org/10.1107/S2056989015000778 Text en © Faizi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Faizi, Md. Serajul Haque
Sharkina, Natalia O.
Davydenko, Yuliya M.
Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium
title Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium
title_full Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium
title_fullStr Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium
title_full_unstemmed Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium
title_short Crystal structure of di­bromido­(N,N-di­methyl­formamide-κO){2-(1H-indol-3-yl)-N-[(quinolin-2-yl-κN)methyl­idene]ethanamine-κN}cadmium
title_sort crystal structure of di­bromido­(n,n-di­methyl­formamide-κo){2-(1h-indol-3-yl)-n-[(quinolin-2-yl-κn)methyl­idene]ethanamine-κn}cadmium
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384581/
https://www.ncbi.nlm.nih.gov/pubmed/25878841
http://dx.doi.org/10.1107/S2056989015000778
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