Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data

In the title compound, [Cu(C(21)H(19)N(6)O(2))Cl], the Cu(II) atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]....

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Detalles Bibliográficos
Autores principales: Kovalchukova, Olga, Nguen, Van, Strashnova, Svetlana, Kuznetsov, Dmitry, Berikashvili, Teimuraz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384589/
https://www.ncbi.nlm.nih.gov/pubmed/25878798
http://dx.doi.org/10.1107/S205698901402756X
Descripción
Sumario:In the title compound, [Cu(C(21)H(19)N(6)O(2))Cl], the Cu(II) atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]. The organic anions act as tridentate chelating ligands. The mol­ecules stack in columns along the c axis.

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