Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data

In the title compound, [Cu(C(21)H(19)N(6)O(2))Cl], the Cu(II) atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]....

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Autores principales: Kovalchukova, Olga, Nguen, Van, Strashnova, Svetlana, Kuznetsov, Dmitry, Berikashvili, Teimuraz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384589/
https://www.ncbi.nlm.nih.gov/pubmed/25878798
http://dx.doi.org/10.1107/S205698901402756X
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author Kovalchukova, Olga
Nguen, Van
Strashnova, Svetlana
Kuznetsov, Dmitry
Berikashvili, Teimuraz
author_facet Kovalchukova, Olga
Nguen, Van
Strashnova, Svetlana
Kuznetsov, Dmitry
Berikashvili, Teimuraz
author_sort Kovalchukova, Olga
collection PubMed
description In the title compound, [Cu(C(21)H(19)N(6)O(2))Cl], the Cu(II) atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]. The organic anions act as tridentate chelating ligands. The mol­ecules stack in columns along the c axis.
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spelling pubmed-43845892015-04-15 Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data Kovalchukova, Olga Nguen, Van Strashnova, Svetlana Kuznetsov, Dmitry Berikashvili, Teimuraz Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Cu(C(21)H(19)N(6)O(2))Cl], the Cu(II) atom is in a slightly distorted square-planar coordination involving two O atoms from the pyrazolone rings [Cu—O = 2.088 (10) and 1.975 (10) Å], an N atom of the azo group [Cu—N = 2.048 (13) Å] and a chloride anion [Cu—Cl = 2.183 (5) Å]. The organic anions act as tridentate chelating ligands. The mol­ecules stack in columns along the c axis. International Union of Crystallography 2015-01-03 /pmc/articles/PMC4384589/ /pubmed/25878798 http://dx.doi.org/10.1107/S205698901402756X Text en © Kovalchukova et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Kovalchukova, Olga
Nguen, Van
Strashnova, Svetlana
Kuznetsov, Dmitry
Berikashvili, Teimuraz
Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data
title Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data
title_full Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data
title_fullStr Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data
title_full_unstemmed Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data
title_short Crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1H-pyrazol-2-ium-4-yl-κO)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1H-pyrazol-4-yl­idene-κO]hydrazin-1-ido-κN (1)}copper(II) from laboratory X-ray powder data
title_sort crystal structure of chlorido­{1-(2,3-dimethyl-5-oxido-1-phenyl-1h-pyrazol-2-ium-4-yl-κo)-2-[3-methyl-5-oxo-1-phenyl-4,5-di­hydro-1h-pyrazol-4-yl­idene-κo]hydrazin-1-ido-κn (1)}copper(ii) from laboratory x-ray powder data
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384589/
https://www.ncbi.nlm.nih.gov/pubmed/25878798
http://dx.doi.org/10.1107/S205698901402756X
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