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Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)

In the title compound, [Cu(C(10)H(11)BrNO)(2)], the asymmetric unit consists of one-half of the mol­ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment...

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Detalles Bibliográficos
Autores principales: Ourari, Ali, Zoubeidi, Chahinaz, Bouacida, Sofiane, Derafa, Wassila, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384597/
https://www.ncbi.nlm.nih.gov/pubmed/25878842
http://dx.doi.org/10.1107/S2056989015001309
Descripción
Sumario:In the title compound, [Cu(C(10)H(11)BrNO)(2)], the asymmetric unit consists of one-half of the mol­ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual mol­ecules are packed in alternating zigzag layers parallel to (001). Weak C—H⋯π inter­actions exist between the mol­ecules.