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Crystal structure of bis(2-{[(3-bromopropyl)imino]methyl}phenolato-κ(2) N,O)copper(II)
In the title compound, [Cu(C(10)H(11)BrNO)(2)], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384597/ https://www.ncbi.nlm.nih.gov/pubmed/25878842 http://dx.doi.org/10.1107/S2056989015001309 |
Sumario: | In the title compound, [Cu(C(10)H(11)BrNO)(2)], the asymmetric unit consists of one-half of the molecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual molecules are packed in alternating zigzag layers parallel to (001). Weak C—H⋯π interactions exist between the molecules. |
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