Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)

In the title compound, [Cu(C(10)H(11)BrNO)(2)], the asymmetric unit consists of one-half of the mol­ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment...

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Autores principales: Ourari, Ali, Zoubeidi, Chahinaz, Bouacida, Sofiane, Derafa, Wassila, Merazig, Hocine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384597/
https://www.ncbi.nlm.nih.gov/pubmed/25878842
http://dx.doi.org/10.1107/S2056989015001309
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author Ourari, Ali
Zoubeidi, Chahinaz
Bouacida, Sofiane
Derafa, Wassila
Merazig, Hocine
author_facet Ourari, Ali
Zoubeidi, Chahinaz
Bouacida, Sofiane
Derafa, Wassila
Merazig, Hocine
author_sort Ourari, Ali
collection PubMed
description In the title compound, [Cu(C(10)H(11)BrNO)(2)], the asymmetric unit consists of one-half of the mol­ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual mol­ecules are packed in alternating zigzag layers parallel to (001). Weak C—H⋯π inter­actions exist between the mol­ecules.
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spelling pubmed-43845972015-04-15 Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II) Ourari, Ali Zoubeidi, Chahinaz Bouacida, Sofiane Derafa, Wassila Merazig, Hocine Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Cu(C(10)H(11)BrNO)(2)], the asymmetric unit consists of one-half of the mol­ecule, the other half being generated by an inversion centre. Hence the Cu(II) cation is symmetrically coordinated by two bidentate Schiff base anions in a slightly distorted square-planar environment with Cu—O and Cu—N bond lengths of 1.8786 (19) and 2.009 (2) Å, respectively. In the crystal, individual mol­ecules are packed in alternating zigzag layers parallel to (001). Weak C—H⋯π inter­actions exist between the mol­ecules. International Union of Crystallography 2015-01-24 /pmc/articles/PMC4384597/ /pubmed/25878842 http://dx.doi.org/10.1107/S2056989015001309 Text en © Ourari et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ourari, Ali
Zoubeidi, Chahinaz
Bouacida, Sofiane
Derafa, Wassila
Merazig, Hocine
Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)
title Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)
title_full Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)
title_fullStr Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)
title_full_unstemmed Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)
title_short Crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) N,O)copper(II)
title_sort crystal structure of bis­(2-{[(3-bromo­prop­yl)imino]­meth­yl}phenolato-κ(2) n,o)copper(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384597/
https://www.ncbi.nlm.nih.gov/pubmed/25878842
http://dx.doi.org/10.1107/S2056989015001309
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