Crystal structure of cholest-5-en-3β-yl 3-(2,4-dimeth­oxy-3-methyl­phen­yl)prop-2-enoate

In the title compound, C(39)H(58)O(4), the steroid rings A and C adopt a chair conformation, while ring B adopts a half-chair conformation, and ring D has an envelope conformation, with the methyl-substituted C atom as the flap. In the crystal, mol­ecules pack within layers parallel to (100), with t...

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Detalles Bibliográficos
Autores principales: Bugenhagen, Bernhard, Munk, Ariane, Vill, Volkmar, Al Jasem, Yosef, Thiemann, Thies
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384600/
https://www.ncbi.nlm.nih.gov/pubmed/25878888
http://dx.doi.org/10.1107/S2056989014028278
Descripción
Sumario:In the title compound, C(39)H(58)O(4), the steroid rings A and C adopt a chair conformation, while ring B adopts a half-chair conformation, and ring D has an envelope conformation, with the methyl-substituted C atom as the flap. In the crystal, mol­ecules pack within layers parallel to (100), with their long axis parallel to the [101] direction. Adjacent layers are linked via C—H⋯O hydrogen bonds and C—H⋯π inter­actions, forming a three-dimensional framework.

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