Crystal structure of β-d,l-allose

The title compound, C(6)H(12)O(6), a C-3 position epimer of glucose, was crystallized from an equimolar mixture of d- and l-allose. It was confirmed that d-allose (l-allose) formed β-pyran­ose with a (4) C (1) ((1) C (4)) conformation in the crystal. In the crystal, molecules are linked by O—H⋯O hyd...

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Autores principales: Ishii, Tomohiko, Senoo, Tatsuya, Kozakai, Taro, Fukada, Kazuhiro, Sakane, Genta
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384602/
https://www.ncbi.nlm.nih.gov/pubmed/25878872
http://dx.doi.org/10.1107/S2056989015000353
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author Ishii, Tomohiko
Senoo, Tatsuya
Kozakai, Taro
Fukada, Kazuhiro
Sakane, Genta
author_facet Ishii, Tomohiko
Senoo, Tatsuya
Kozakai, Taro
Fukada, Kazuhiro
Sakane, Genta
author_sort Ishii, Tomohiko
collection PubMed
description The title compound, C(6)H(12)O(6), a C-3 position epimer of glucose, was crystallized from an equimolar mixture of d- and l-allose. It was confirmed that d-allose (l-allose) formed β-pyran­ose with a (4) C (1) ((1) C (4)) conformation in the crystal. In the crystal, molecules are linked by O—H⋯O hydrogen bond, forming a three-dimensional framework. The cell volume of the racemic β-d,l-allose is 739.36 (3) Å(3), which is about 10 Å(3) smaller than that of chiral β-d-allose [V = 751.0 (2) Å(3)].
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spelling pubmed-43846022015-04-15 Crystal structure of β-d,l-allose Ishii, Tomohiko Senoo, Tatsuya Kozakai, Taro Fukada, Kazuhiro Sakane, Genta Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(6)H(12)O(6), a C-3 position epimer of glucose, was crystallized from an equimolar mixture of d- and l-allose. It was confirmed that d-allose (l-allose) formed β-pyran­ose with a (4) C (1) ((1) C (4)) conformation in the crystal. In the crystal, molecules are linked by O—H⋯O hydrogen bond, forming a three-dimensional framework. The cell volume of the racemic β-d,l-allose is 739.36 (3) Å(3), which is about 10 Å(3) smaller than that of chiral β-d-allose [V = 751.0 (2) Å(3)]. International Union of Crystallography 2015-01-31 /pmc/articles/PMC4384602/ /pubmed/25878872 http://dx.doi.org/10.1107/S2056989015000353 Text en © Ishii et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ishii, Tomohiko
Senoo, Tatsuya
Kozakai, Taro
Fukada, Kazuhiro
Sakane, Genta
Crystal structure of β-d,l-allose
title Crystal structure of β-d,l-allose
title_full Crystal structure of β-d,l-allose
title_fullStr Crystal structure of β-d,l-allose
title_full_unstemmed Crystal structure of β-d,l-allose
title_short Crystal structure of β-d,l-allose
title_sort crystal structure of β-d,l-allose
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384602/
https://www.ncbi.nlm.nih.gov/pubmed/25878872
http://dx.doi.org/10.1107/S2056989015000353
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AT senootatsuya crystalstructureofbdlallose
AT kozakaitaro crystalstructureofbdlallose
AT fukadakazuhiro crystalstructureofbdlallose
AT sakanegenta crystalstructureofbdlallose

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