Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate

In the title salt, [Ag(CH(4)N(2)S)(2)(PPh(3))(2)]NO(3), the Ag(I) atom is coordinated by two thio­urea S atoms and two tri­phenyl­phosphane P atoms in a distorted tetra­hedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In...

Descripción completa

Detalles Bibliográficos
Autores principales: Nawaz, Sidra, Tahir, Muhammad Nawaz, Nadeem, Muhammad Amir, Mehmood, Bushra, Ahmad, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384606/
https://www.ncbi.nlm.nih.gov/pubmed/25878824
http://dx.doi.org/10.1107/S2056989015001395
Descripción
Sumario:In the title salt, [Ag(CH(4)N(2)S)(2)(PPh(3))(2)]NO(3), the Ag(I) atom is coordinated by two thio­urea S atoms and two tri­phenyl­phosphane P atoms in a distorted tetra­hedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C—H⋯O, C—H⋯S, N—H⋯O and N—H⋯S hydrogen bonds, generating (10-1) sheets.

Ejemplares similares