Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate

In the title salt, [Ag(CH(4)N(2)S)(2)(PPh(3))(2)]NO(3), the Ag(I) atom is coordinated by two thio­urea S atoms and two tri­phenyl­phosphane P atoms in a distorted tetra­hedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In...

Descripción completa

Detalles Bibliográficos
Autores principales: Nawaz, Sidra, Tahir, Muhammad Nawaz, Nadeem, Muhammad Amir, Mehmood, Bushra, Ahmad, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384606/
https://www.ncbi.nlm.nih.gov/pubmed/25878824
http://dx.doi.org/10.1107/S2056989015001395
_version_ 1782364930396127232
author Nawaz, Sidra
Tahir, Muhammad Nawaz
Nadeem, Muhammad Amir
Mehmood, Bushra
Ahmad, Saeed
author_facet Nawaz, Sidra
Tahir, Muhammad Nawaz
Nadeem, Muhammad Amir
Mehmood, Bushra
Ahmad, Saeed
author_sort Nawaz, Sidra
collection PubMed
description In the title salt, [Ag(CH(4)N(2)S)(2)(PPh(3))(2)]NO(3), the Ag(I) atom is coordinated by two thio­urea S atoms and two tri­phenyl­phosphane P atoms in a distorted tetra­hedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C—H⋯O, C—H⋯S, N—H⋯O and N—H⋯S hydrogen bonds, generating (10-1) sheets.
format Online
Article
Text
id pubmed-4384606
institution National Center for Biotechnology Information
language English
publishDate 2015
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-43846062015-04-15 Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate Nawaz, Sidra Tahir, Muhammad Nawaz Nadeem, Muhammad Amir Mehmood, Bushra Ahmad, Saeed Acta Crystallogr E Crystallogr Commun Research Communications In the title salt, [Ag(CH(4)N(2)S)(2)(PPh(3))(2)]NO(3), the Ag(I) atom is coordinated by two thio­urea S atoms and two tri­phenyl­phosphane P atoms in a distorted tetra­hedral geometry, with bond angles in the range 102.90 (4)–123.29 (4)°. The Ag—S=C bond angles are 101.75 (19) and 111.29 (18)°. In the crystal, the component ions are linked by C—H⋯O, C—H⋯S, N—H⋯O and N—H⋯S hydrogen bonds, generating (10-1) sheets. International Union of Crystallography 2015-01-28 /pmc/articles/PMC4384606/ /pubmed/25878824 http://dx.doi.org/10.1107/S2056989015001395 Text en © Nawaz et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Nawaz, Sidra
Tahir, Muhammad Nawaz
Nadeem, Muhammad Amir
Mehmood, Bushra
Ahmad, Saeed
Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_full Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_fullStr Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_full_unstemmed Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_short Crystal structure of bis­(thio­urea-κS)bis­(tri­phenylphosphane-κP)silver(I) nitrate
title_sort crystal structure of bis­(thio­urea-κs)bis­(tri­phenylphosphane-κp)silver(i) nitrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384606/
https://www.ncbi.nlm.nih.gov/pubmed/25878824
http://dx.doi.org/10.1107/S2056989015001395
work_keys_str_mv AT nawazsidra crystalstructureofbisthioureaksbistriphenylphosphanekpsilverinitrate
AT tahirmuhammadnawaz crystalstructureofbisthioureaksbistriphenylphosphanekpsilverinitrate
AT nadeemmuhammadamir crystalstructureofbisthioureaksbistriphenylphosphanekpsilverinitrate
AT mehmoodbushra crystalstructureofbisthioureaksbistriphenylphosphanekpsilverinitrate
AT ahmadsaeed crystalstructureofbisthioureaksbistriphenylphosphanekpsilverinitrate

Ejemplares similares