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Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO
The molecular structure of (acetone-κO)tris(μ-ferrocene-1,1′-dicarbonitrile-κ(2) N:N′)dicopper(I) bis(tetrafluoridoborate) acetone monosolvate, [Cu(2)Fe(3)(C(6)H(4)N)(6)(C(3)H(6)O)](BF(4))(2)·C(3)H(6)O, consists of two Cu(I) ions bridged by a ferrocene-1,1′-dicarbonitrile moiety in a paddle-w...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384607/ https://www.ncbi.nlm.nih.gov/pubmed/25878831 http://dx.doi.org/10.1107/S2056989015001760 |
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author | Strehler, Frank Korb, Marcus Lang, Heinrich |
author_facet | Strehler, Frank Korb, Marcus Lang, Heinrich |
author_sort | Strehler, Frank |
collection | PubMed |
description | The molecular structure of (acetone-κO)tris(μ-ferrocene-1,1′-dicarbonitrile-κ(2) N:N′)dicopper(I) bis(tetrafluoridoborate) acetone monosolvate, [Cu(2)Fe(3)(C(6)H(4)N)(6)(C(3)H(6)O)](BF(4))(2)·C(3)H(6)O, consists of two Cu(I) ions bridged by a ferrocene-1,1′-dicarbonitrile moiety in a paddle-wheel-architectured sandwich complex with two BF(4) (−) units as counter-ions. One of the latter is equally disordered over two sets of sites. The two Cu(I) ions are complexed in a trigonal–planar manner by three nitrile N-donor atoms. Further interactions by the O atom of an acetone molecule to one of the Cu(I) atoms and a weak η(2),π-interaction of two atoms of a cyclopentadienyl ring to the other Cu(I) atom complete a distorted trigonal–pyramidal environment for each of the metal ions. A further acetone molecule is also present as a solvent molecule. The crystal packing is consolidated by several π–π interactions. |
format | Online Article Text |
id | pubmed-4384607 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43846072015-04-15 Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO Strehler, Frank Korb, Marcus Lang, Heinrich Acta Crystallogr E Crystallogr Commun Research Communications The molecular structure of (acetone-κO)tris(μ-ferrocene-1,1′-dicarbonitrile-κ(2) N:N′)dicopper(I) bis(tetrafluoridoborate) acetone monosolvate, [Cu(2)Fe(3)(C(6)H(4)N)(6)(C(3)H(6)O)](BF(4))(2)·C(3)H(6)O, consists of two Cu(I) ions bridged by a ferrocene-1,1′-dicarbonitrile moiety in a paddle-wheel-architectured sandwich complex with two BF(4) (−) units as counter-ions. One of the latter is equally disordered over two sets of sites. The two Cu(I) ions are complexed in a trigonal–planar manner by three nitrile N-donor atoms. Further interactions by the O atom of an acetone molecule to one of the Cu(I) atoms and a weak η(2),π-interaction of two atoms of a cyclopentadienyl ring to the other Cu(I) atom complete a distorted trigonal–pyramidal environment for each of the metal ions. A further acetone molecule is also present as a solvent molecule. The crystal packing is consolidated by several π–π interactions. International Union of Crystallography 2015-01-31 /pmc/articles/PMC4384607/ /pubmed/25878831 http://dx.doi.org/10.1107/S2056989015001760 Text en © Strehler et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Strehler, Frank Korb, Marcus Lang, Heinrich Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO |
title | Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO |
title_full | Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO |
title_fullStr | Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO |
title_full_unstemmed | Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO |
title_short | Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO |
title_sort | crystal structure of paddle-wheel sandwich-type [cu(2){(ch(3))(2)co}{μ-fe(η(5)-c(5)h(4)c n)(2)}(3)](bf(4))(2)·(ch(3))(2)co |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384607/ https://www.ncbi.nlm.nih.gov/pubmed/25878831 http://dx.doi.org/10.1107/S2056989015001760 |
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