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Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO

The mol­ecular structure of (acetone-κO)tris­(μ-ferrocene-1,1′-dicarbo­nitrile-κ(2) N:N′)dicopper(I) bis­(tetra­fluorido­borate) acetone monosolvate, [Cu(2)Fe(3)(C(6)H(4)N)(6)(C(3)H(6)O)](BF(4))(2)·C(3)H(6)O, consists of two Cu(I) ions bridged by a ferrocene-1,1′-dicarbo­nitrile moiety in a paddle-w...

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Detalles Bibliográficos
Autores principales: Strehler, Frank, Korb, Marcus, Lang, Heinrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384607/
https://www.ncbi.nlm.nih.gov/pubmed/25878831
http://dx.doi.org/10.1107/S2056989015001760
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author Strehler, Frank
Korb, Marcus
Lang, Heinrich
author_facet Strehler, Frank
Korb, Marcus
Lang, Heinrich
author_sort Strehler, Frank
collection PubMed
description The mol­ecular structure of (acetone-κO)tris­(μ-ferrocene-1,1′-dicarbo­nitrile-κ(2) N:N′)dicopper(I) bis­(tetra­fluorido­borate) acetone monosolvate, [Cu(2)Fe(3)(C(6)H(4)N)(6)(C(3)H(6)O)](BF(4))(2)·C(3)H(6)O, consists of two Cu(I) ions bridged by a ferrocene-1,1′-dicarbo­nitrile moiety in a paddle-wheel-architectured sandwich complex with two BF(4) (−) units as counter-ions. One of the latter is equally disordered over two sets of sites. The two Cu(I) ions are complexed in a trigonal–planar manner by three nitrile N-donor atoms. Further inter­actions by the O atom of an acetone mol­ecule to one of the Cu(I) atoms and a weak η(2),π-inter­action of two atoms of a cyclo­penta­dienyl ring to the other Cu(I) atom complete a distorted trigonal–pyramidal environment for each of the metal ions. A further acetone mol­ecule is also present as a solvent mol­ecule. The crystal packing is consolidated by several π–π inter­actions.
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spelling pubmed-43846072015-04-15 Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO Strehler, Frank Korb, Marcus Lang, Heinrich Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of (acetone-κO)tris­(μ-ferrocene-1,1′-dicarbo­nitrile-κ(2) N:N′)dicopper(I) bis­(tetra­fluorido­borate) acetone monosolvate, [Cu(2)Fe(3)(C(6)H(4)N)(6)(C(3)H(6)O)](BF(4))(2)·C(3)H(6)O, consists of two Cu(I) ions bridged by a ferrocene-1,1′-dicarbo­nitrile moiety in a paddle-wheel-architectured sandwich complex with two BF(4) (−) units as counter-ions. One of the latter is equally disordered over two sets of sites. The two Cu(I) ions are complexed in a trigonal–planar manner by three nitrile N-donor atoms. Further inter­actions by the O atom of an acetone mol­ecule to one of the Cu(I) atoms and a weak η(2),π-inter­action of two atoms of a cyclo­penta­dienyl ring to the other Cu(I) atom complete a distorted trigonal–pyramidal environment for each of the metal ions. A further acetone mol­ecule is also present as a solvent mol­ecule. The crystal packing is consolidated by several π–π inter­actions. International Union of Crystallography 2015-01-31 /pmc/articles/PMC4384607/ /pubmed/25878831 http://dx.doi.org/10.1107/S2056989015001760 Text en © Strehler et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Strehler, Frank
Korb, Marcus
Lang, Heinrich
Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO
title Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO
title_full Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO
title_fullStr Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO
title_full_unstemmed Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO
title_short Crystal structure of paddle-wheel sandwich-type [Cu(2){(CH(3))(2)CO}{μ-Fe(η(5)-C(5)H(4)C N)(2)}(3)](BF(4))(2)·(CH(3))(2)CO
title_sort crystal structure of paddle-wheel sandwich-type [cu(2){(ch(3))(2)co}{μ-fe(η(5)-c(5)h(4)c n)(2)}(3)](bf(4))(2)·(ch(3))(2)co
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384607/
https://www.ncbi.nlm.nih.gov/pubmed/25878831
http://dx.doi.org/10.1107/S2056989015001760
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