Crystal structure of methyl N-ferro­cenyl­carbamate

The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)NO(2))], contains two independent mol­ecules consisting of a ferrocenyl moiety and a nitro­gen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74 (9) and 87.32 (8)°. In each inde...

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Detalles Bibliográficos
Autores principales: Rodríguez, Alan J., Quirke, J. Martin. E., Diouf, Aida O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384608/
https://www.ncbi.nlm.nih.gov/pubmed/25878840
http://dx.doi.org/10.1107/S2056989015000043
Descripción
Sumario:The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)NO(2))], contains two independent mol­ecules consisting of a ferrocenyl moiety and a nitro­gen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74 (9) and 87.32 (8)°. In each independent mol­ecule, the cyclo­penta­dienyl rings deviate slightly from an eclipsed conformation and lie virtually parallel [dihedral angles = 1.42 (15) and 0.49 (13)°]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into chains along the a-axis direction.

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