Crystal structure of methyl N-ferro­cenyl­carbamate

The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)NO(2))], contains two independent mol­ecules consisting of a ferrocenyl moiety and a nitro­gen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74 (9) and 87.32 (8)°. In each inde...

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Autores principales: Rodríguez, Alan J., Quirke, J. Martin. E., Diouf, Aida O.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384608/
https://www.ncbi.nlm.nih.gov/pubmed/25878840
http://dx.doi.org/10.1107/S2056989015000043
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author Rodríguez, Alan J.
Quirke, J. Martin. E.
Diouf, Aida O.
author_facet Rodríguez, Alan J.
Quirke, J. Martin. E.
Diouf, Aida O.
author_sort Rodríguez, Alan J.
collection PubMed
description The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)NO(2))], contains two independent mol­ecules consisting of a ferrocenyl moiety and a nitro­gen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74 (9) and 87.32 (8)°. In each independent mol­ecule, the cyclo­penta­dienyl rings deviate slightly from an eclipsed conformation and lie virtually parallel [dihedral angles = 1.42 (15) and 0.49 (13)°]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into chains along the a-axis direction.
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spelling pubmed-43846082015-04-15 Crystal structure of methyl N-ferro­cenyl­carbamate Rodríguez, Alan J. Quirke, J. Martin. E. Diouf, Aida O. Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)NO(2))], contains two independent mol­ecules consisting of a ferrocenyl moiety and a nitro­gen-bound methyl carbamate. These units are almost perpendicular to each other, making dihedral angles of 87.74 (9) and 87.32 (8)°. In each independent mol­ecule, the cyclo­penta­dienyl rings deviate slightly from an eclipsed conformation and lie virtually parallel [dihedral angles = 1.42 (15) and 0.49 (13)°]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds into chains along the a-axis direction. International Union of Crystallography 2015-01-17 /pmc/articles/PMC4384608/ /pubmed/25878840 http://dx.doi.org/10.1107/S2056989015000043 Text en © Rodríguez et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Rodríguez, Alan J.
Quirke, J. Martin. E.
Diouf, Aida O.
Crystal structure of methyl N-ferro­cenyl­carbamate
title Crystal structure of methyl N-ferro­cenyl­carbamate
title_full Crystal structure of methyl N-ferro­cenyl­carbamate
title_fullStr Crystal structure of methyl N-ferro­cenyl­carbamate
title_full_unstemmed Crystal structure of methyl N-ferro­cenyl­carbamate
title_short Crystal structure of methyl N-ferro­cenyl­carbamate
title_sort crystal structure of methyl n-ferro­cenyl­carbamate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384608/
https://www.ncbi.nlm.nih.gov/pubmed/25878840
http://dx.doi.org/10.1107/S2056989015000043
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