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Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one
The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the C=N bond. The two molecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-meth...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384611/ https://www.ncbi.nlm.nih.gov/pubmed/25878856 http://dx.doi.org/10.1107/S205698901500033X |
Sumario: | The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the C=N bond. The two molecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-methoxybenzene ring is inclined to the central benzene ring and the outer 4-acetylbenzene ring by 1.80 (19) and 63.73 (19)°, respectively, in molecule A, and by 6.72 (18) and 68.53 (19)°, respectively, in molecule B. The two outer benzene rings are inclined to one another by 63.77 (18) and 63.19 (18)° in molecules A and B, respectively. In the crystal, the individual molecules stack in columns along [010], and are linked by a number of C—H⋯π interactions, forming slabs lying parallel to (001). |
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