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Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one

The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules have an E conformation about the C=N bond. The two mol­ecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-meth­...

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Autores principales: Hebbachi, Rabihe, Djedouani, Amel, Kadri, Soumia, Mousser, Hénia, Mousser, Abdelhamid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384611/
https://www.ncbi.nlm.nih.gov/pubmed/25878856
http://dx.doi.org/10.1107/S205698901500033X
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author Hebbachi, Rabihe
Djedouani, Amel
Kadri, Soumia
Mousser, Hénia
Mousser, Abdelhamid
author_facet Hebbachi, Rabihe
Djedouani, Amel
Kadri, Soumia
Mousser, Hénia
Mousser, Abdelhamid
author_sort Hebbachi, Rabihe
collection PubMed
description The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules have an E conformation about the C=N bond. The two mol­ecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-meth­oxy­benzene ring is inclined to the central benzene ring and the outer 4-acetyl­benzene ring by 1.80 (19) and 63.73 (19)°, respectively, in mol­ecule A, and by 6.72 (18) and 68.53 (19)°, respectively, in mol­ecule B. The two outer benzene rings are inclined to one another by 63.77 (18) and 63.19 (18)° in mol­ecules A and B, respectively. In the crystal, the individual mol­ecules stack in columns along [010], and are linked by a number of C—H⋯π inter­actions, forming slabs lying parallel to (001).
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spelling pubmed-43846112015-04-15 Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one Hebbachi, Rabihe Djedouani, Amel Kadri, Soumia Mousser, Hénia Mousser, Abdelhamid Acta Crystallogr E Crystallogr Commun Data Reports The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules have an E conformation about the C=N bond. The two mol­ecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-meth­oxy­benzene ring is inclined to the central benzene ring and the outer 4-acetyl­benzene ring by 1.80 (19) and 63.73 (19)°, respectively, in mol­ecule A, and by 6.72 (18) and 68.53 (19)°, respectively, in mol­ecule B. The two outer benzene rings are inclined to one another by 63.77 (18) and 63.19 (18)° in mol­ecules A and B, respectively. In the crystal, the individual mol­ecules stack in columns along [010], and are linked by a number of C—H⋯π inter­actions, forming slabs lying parallel to (001). International Union of Crystallography 2015-01-14 /pmc/articles/PMC4384611/ /pubmed/25878856 http://dx.doi.org/10.1107/S205698901500033X Text en © Hebbachi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hebbachi, Rabihe
Djedouani, Amel
Kadri, Soumia
Mousser, Hénia
Mousser, Abdelhamid
Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one
title Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one
title_full Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one
title_fullStr Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one
title_full_unstemmed Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one
title_short Crystal structure of (E)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one
title_sort crystal structure of (e)-1-[4-({4-[(4-meth­oxy­benzyl­idene)amino]­phen­yl}sulfan­yl)phen­yl]ethan-1-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384611/
https://www.ncbi.nlm.nih.gov/pubmed/25878856
http://dx.doi.org/10.1107/S205698901500033X
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