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Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one
The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the C=N bond. The two molecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-meth...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384611/ https://www.ncbi.nlm.nih.gov/pubmed/25878856 http://dx.doi.org/10.1107/S205698901500033X |
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author | Hebbachi, Rabihe Djedouani, Amel Kadri, Soumia Mousser, Hénia Mousser, Abdelhamid |
author_facet | Hebbachi, Rabihe Djedouani, Amel Kadri, Soumia Mousser, Hénia Mousser, Abdelhamid |
author_sort | Hebbachi, Rabihe |
collection | PubMed |
description | The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the C=N bond. The two molecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-methoxybenzene ring is inclined to the central benzene ring and the outer 4-acetylbenzene ring by 1.80 (19) and 63.73 (19)°, respectively, in molecule A, and by 6.72 (18) and 68.53 (19)°, respectively, in molecule B. The two outer benzene rings are inclined to one another by 63.77 (18) and 63.19 (18)° in molecules A and B, respectively. In the crystal, the individual molecules stack in columns along [010], and are linked by a number of C—H⋯π interactions, forming slabs lying parallel to (001). |
format | Online Article Text |
id | pubmed-4384611 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43846112015-04-15 Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one Hebbachi, Rabihe Djedouani, Amel Kadri, Soumia Mousser, Hénia Mousser, Abdelhamid Acta Crystallogr E Crystallogr Commun Data Reports The title Schiff base compound, C(22)H(19)NO(2)S, crystallized with two independent molecules (A and B) in the asymmetric unit. Both molecules have an E conformation about the C=N bond. The two molecules differ in the orientation of the aromatic rings with respect to each other. The outer 4-methoxybenzene ring is inclined to the central benzene ring and the outer 4-acetylbenzene ring by 1.80 (19) and 63.73 (19)°, respectively, in molecule A, and by 6.72 (18) and 68.53 (19)°, respectively, in molecule B. The two outer benzene rings are inclined to one another by 63.77 (18) and 63.19 (18)° in molecules A and B, respectively. In the crystal, the individual molecules stack in columns along [010], and are linked by a number of C—H⋯π interactions, forming slabs lying parallel to (001). International Union of Crystallography 2015-01-14 /pmc/articles/PMC4384611/ /pubmed/25878856 http://dx.doi.org/10.1107/S205698901500033X Text en © Hebbachi et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Hebbachi, Rabihe Djedouani, Amel Kadri, Soumia Mousser, Hénia Mousser, Abdelhamid Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one |
title | Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one |
title_full | Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one |
title_fullStr | Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one |
title_full_unstemmed | Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one |
title_short | Crystal structure of (E)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one |
title_sort | crystal structure of (e)-1-[4-({4-[(4-methoxybenzylidene)amino]phenyl}sulfanyl)phenyl]ethan-1-one |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384611/ https://www.ncbi.nlm.nih.gov/pubmed/25878856 http://dx.doi.org/10.1107/S205698901500033X |
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