Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV)

Reaction of oxalic acid and di­phenyl­tin dichloride in the presence of cyclo­hexyl­amine led to the formation of the title salt, (C(6)H(14)N)(2)[Sn(C(6)H(5))(2)(C(2)O(4))(2)]. The dianion is made up from an Sn(C(6)H(5))(2) moiety cis-coordinated by two chelating oxalate anions, leading to an overal...

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Autores principales: Sarr, Modou, Diasse-Sarr, Aminata, Diop, Libasse, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384614/
https://www.ncbi.nlm.nih.gov/pubmed/25878805
http://dx.doi.org/10.1107/S2056989014027716
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author Sarr, Modou
Diasse-Sarr, Aminata
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
author_facet Sarr, Modou
Diasse-Sarr, Aminata
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
author_sort Sarr, Modou
collection PubMed
description Reaction of oxalic acid and di­phenyl­tin dichloride in the presence of cyclo­hexyl­amine led to the formation of the title salt, (C(6)H(14)N)(2)[Sn(C(6)H(5))(2)(C(2)O(4))(2)]. The dianion is made up from an Sn(C(6)H(5))(2) moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octa­hedral coordination geometry of the Sn(IV) atom. The negative charges are compensated by two surrounding cyclo­hexyl­ammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N—H⋯O hydrogen bonds into a layered arrangement parallel to (101).
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spelling pubmed-43846142015-04-15 Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV) Sarr, Modou Diasse-Sarr, Aminata Diop, Libasse Plasseraud, Laurent Cattey, Hélène Acta Crystallogr E Crystallogr Commun Research Communications Reaction of oxalic acid and di­phenyl­tin dichloride in the presence of cyclo­hexyl­amine led to the formation of the title salt, (C(6)H(14)N)(2)[Sn(C(6)H(5))(2)(C(2)O(4))(2)]. The dianion is made up from an Sn(C(6)H(5))(2) moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octa­hedral coordination geometry of the Sn(IV) atom. The negative charges are compensated by two surrounding cyclo­hexyl­ammonium cations adopting chair conformations each. In the crystal, anions and cations are linked via a network of N—H⋯O hydrogen bonds into a layered arrangement parallel to (101). International Union of Crystallography 2015-01-10 /pmc/articles/PMC4384614/ /pubmed/25878805 http://dx.doi.org/10.1107/S2056989014027716 Text en © Sarr et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Sarr, Modou
Diasse-Sarr, Aminata
Diop, Libasse
Plasseraud, Laurent
Cattey, Hélène
Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV)
title Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV)
title_full Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV)
title_fullStr Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV)
title_full_unstemmed Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV)
title_short Crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(IV)
title_sort crystal structure of bis­(cyclo­hexyl­ammonium) di­phenyl­dioxalatostannate(iv)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4384614/
https://www.ncbi.nlm.nih.gov/pubmed/25878805
http://dx.doi.org/10.1107/S2056989014027716
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